Pressure Management for Slurry Polymerization

ABSTRACT

Processes and systems for the production for pressure management of a polymerization product flowing from a loop polymerization reactor to a separation vessel in a slurry polymerization system are disclosed herein. For example, a process comprises withdrawing a polymerization product slurry from a loop polymerization reactor, conveying the polymerization product slurry through a first line comprising a continuous take-off valve to yield a mixture comprising a vapor phase, wherein the mixture exits the continuous take-off valve, and conveying the mixture through a second line comprising a flashline heater so that the mixture has a Froude number in a range from about 5 to about 100.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation-in-part of and claims priority toU.S. patent application Ser. No. 13/778,881 filed on Feb. 27, 2013, andentitled “Pressure Management for Slurry Polymerization,” which is acontinuation of and claims priority to U.S. patent application Ser. No.13/664,944 filed on Oct. 31, 2012, and entitled “Pressure Management forSlurry Polymerization,” each of which is incorporated by referenceherein in its entirety.

STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT

Not applicable.

REFERENCE TO A MICROFICHE APPENDIX

Not applicable.

FIELD

This disclosure relates to the control of pressures downstream of apolymerization reactor.

BACKGROUND

Polyolefins such as polyethylene and polypropylene may be prepared byslurry polymerization. In this technique, feed materials such asdiluent, monomer and catalyst are introduced to a loop reaction zone,forming a slurry in the reaction zone, in continuous loop reactors, theslurry circulates through the loop reaction zone, and the monomer reactsat the catalyst in a polymerization reaction. The polymerizationreaction yields solid polyolefins in the slurry. A polymerizationproduct having solid polyolefins is then transferred from the reactorand separated to recover the solid polyolefins. Operating pressuresduring transfer of the product can affect recovery of solid polyolefins;thus, pressure management can be important.

SUMMARY

Disclosed herein is a process for pressure management of apolymerization product in slurry polymerization, comprising withdrawinga polymerization product slurry from a loop polymerization reactor,conveying the polymerization product slurry through a first linecomprising a continuous take-off valve to yield a mixture comprising avapor phase, wherein the mixture exits the continuous take-off valve,and conveying the mixture through a second line comprising a flashlineheater so that the mixture has a Froude number in a range from about 5to about 100.

Also disclosed herein is a process for pressure management of apolymerization product slurry withdrawn from a loop polymerizationreactor in slurry polymerization, comprising conveying thepolymerization product slurry through a continuous take-off valve,converting the polymerization product slurry to a mixture comprising avapor phase, wherein the mixture exits the continuous take-off valve,and conveying the mixture through a flashline heater, wherein themixture in the flashline heater has a Froude number in a range of 5 to100.

Also disclosed herein is a system for pressure management of apolymerization product in a loop polymerization process, comprising apolymerization reactor to form the polymerization product, a first linecomprising a continuous take-off valve, wherein the first line receivesa polymerization product slurry from the loop slurry polymerizationreactor, wherein at least a portion of the polymerization product slurryconverts to a mixture comprising a vapor phase which exits thecontinuous take-off valve, a second line comprising a flashline heater,wherein the second line receives a mixture from the first line, and aseparation vessel to receive the mixture from the second line. A firstpressure differential may be associated with the first line, a secondpressure differential may be associated with the second line, the firstpressure differential may be less than or greater than the secondpressure differential, and a solid polymer may be recovered from theseparation vessel.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows a process flow diagram of an embodiment of a system forpressure management of a polymerization product in a loop polymerizationprocess.

FIG. 2 shows a process flow diagram of another embodiment of a systemfor pressure management of a polymerization product in a looppolymerization process.

FIG. 3 shows a cross-sectional view of an embodiment of a portion of theflashline heater, taken along sight line 3-3 of FIG. 2.

DETAILED DESCRIPTION OF THE EMBODIMENTS

Disclosed herein are embodiments of a system for pressure management ofa polymerization product in a loop polymerization process. Additionally,disclosed herein are various methods for pressure management of apolymerization product flowing from a loop polymerization reactor to aseparation vessel in slurry polymerization.

FIG. 1 shows a process flow diagram of an embodiment of a system 100 forpressure management of a polymerization product in a loop polymerizationprocess. The system 100 may comprise a loop slurry polymerizationreactor 110 which forms polymerization product, a first line 120 whichreceives a polymerization product (e.g., as a polymerization productslurry) from the loop slurry polymerization reactor 110, a second line130 which receives the polymerization product (e.g., as thepolymerization product slurry) from the first line 120, and a separationvessel 140 which receives the polymerization product (e.g., as thepolymerization product slurry) from the second line 130. Solid polymermay be recovered from the separation vessel 140.

As disclosed above, the system 100 may comprise a loop slurrypolymerization reactor 110. In one or more of the embodiments disclosedherein, the reactor 110 may comprise any vessel or combination ofvessels suitably configured to provide an environment for a chemicalreaction (e.g., a contact zone) between monomers (e.g., ethylene) and/orpolymers (e.g., an “active” or growing polymer chain), and optionallycomonomers (e.g., butene-1, hexene) and/or copolymers, in the presenceof a catalyst to yield a polymer (e.g., a polyethylene polymer) and/orcopolymer. Although the embodiment illustrated in FIG. 1 shows a singlereactor 110, one of skill in the art viewing this disclosure willrecognize that any suitable number and/or configuration of reactors maybe employed.

As used herein, the terms “polymerization reactor” or “reactor” mayinclude at least one loop slurry polymerization reactor capable ofpolymerizing olefin monomers or comonomers to produce homopolymers orcopolymers. Such homopolymers and copolymers are referred to as resinsor polymers.

The polymerization processes performed in the reactor(s) (e.g., reactor110) may include batch or continuous processes. Continuous processescould use intermittent or continuous product discharge. Processes mayalso include partial or full direct recycle of unreacted monomer,unreacted comonomer, and/or diluent.

In embodiments having multiple reactors, production of polymerizationproduct in multiple reactors may include several stages in at least twoseparate polymerization reactors interconnected by a transfer devicemaking it possible to transfer the polymerization product resulting froma first polymerization reactor into a second reactor (e.g., loop slurrypolymerization reactor 110). The desired polymerization conditions inone reactor may be different from the polymerization conditions of theother reactor(s). Alternatively, polymerization in multiple reactors mayinclude the manual transfer of polymerization product (e.g., in apolymerization product slurry, as a mixture, as solid polymer, orcombinations thereof) from one reactor to subsequent reactors forcontinued polymerization. Multiple reactor systems may include anycombination including, but not limited to, multiple loop reactors, acombination of loop and gas reactors, multiple high pressure reactors ora combination of high pressure with loop and/or gas reactors. Themultiple reactors may be operated in series, in parallel, orcombinations thereof.

According to one aspect, the loop slurry polymerization reactor 110 maycomprise vertical or horizontal pipes 112 and 114 interconnected bysmooth bends or elbows 115, which together form a loop. Portions of theloop slurry polymerization reactor 110, such as pipes 112, may havecooling jackets 113 placed therearound to remove excess heat generatedby the exothermic polymerization reactions. A cooling fluid may becirculated through jackets 113, for example.

A motive device, such as pump 150, may circulate the fluid slurry in theloop slurry polymerization reactor 110. An example of the pump 150 is anin-line axial flow pump with a pump impeller 152 disposed within theinterior of the reactor 140. The impeller 152 may, during operation,create a turbulent mixing zone within a fluid medium circulating throughthe reactor 110 such that sufficient contact between differentpolymerization components within the slurry may occur. The impeller 152may also assist in propelling the slurry through the closed loop of thereactor 110 at sufficient speed to keep solid particulates, such as thecatalyst or polymerization product, suspended within the slurry. Theimpeller 152 may be driven by a motor 154 or other motive force.

The system 100 may additionally comprise any equipment associated with apolymerization reactor, such as pumps, control devices (e.g., a PIDcontroller), measurement instruments (e.g., thermocouples, transducers,and flow meters), alternative inlet and outlet lines, etc.

Monomer, diluent, catalyst, and optionally any comonomer, which may befed to the slurry loop polymerization reactor 110 (e.g., via feed stream102), may circulate through the loop as polymerization occurs.Generally, continuous processes may comprise the continuous introductionof a monomer, an optional comonomer, a catalyst, and a diluent into theloop slurry polymerization reactor 110 and the continuous removal (e.g.,via first line 120) of a slurry comprising solid polymer (e.g.,polyethylene) and a liquid phase of the diluent.

In one or more embodiments, a comonomer may comprise unsaturatedhydrocarbons having 3 to 12 carbon atoms. For example, a comonomer maycomprise propene, butene-1, hexene-1, octenes, or combinations thereof.

In embodiments, suitable diluents used in slurry polymerizationprocesses may include, but are not limited to, the monomer, andoptionally, the comonomer, being polymerized and hydrocarbons that areliquids under reaction conditions. Examples of suitable diluentsinclude, but are not limited to, hydrocarbons such as propane,cyclohexane, isobutane, n-butane, n-pentane, isopentane, neopentane, andn-hexane. In embodiments, diluents may comprise unsaturated hydrocarbonshaving 3 to 12 carbon atoms. Further examples of suitable diluentsinclude, but are not limited to propene, butene-1, hexene-1, octenes, orcombinations thereof. Some loop polymerization reactions can occur underbulk conditions where no diluent is used. An example is polymerizationof propylene monomer as disclosed in U.S. Pat. No. 5,455,314, which isincorporated by reference herein in its entirety.

A typical loop polymerization process is disclosed, for example, in U.S.Pat. Nos. 3,248,179, 4,501,885, 5,565,175, 5,575,979, 6,239,235,6,262,191 and 6,833,415, each of which is incorporated by reference inits entirety herein.

In embodiments having multiple reactors, various types of reactors thatmay additionally be included in system 100 may comprise gas-phasereactors. Gas-phase reactors may comprise fluidized bed reactors orstaged horizontal reactors. Gas-phase reactors may employ a continuousrecycle stream containing one or more monomers continuously cycledthrough a fluidized bed in the presence of the catalyst underpolymerization conditions. A recycle stream may be withdrawn from thefluidized bed and recycled back into the reactor. Simultaneously,polymer product may be withdrawn from the reactor and new or freshmonomer may be added to replace the polymerized monomer. Likewise,copolymer product may optionally be withdrawn from the reactor and newor fresh comonomer may be added to replace polymerized comonomer,polymerized monomer, or combinations thereof. Such gas phase reactorsmay comprise a process for multi-step gas-phase polymerization ofolefins, in which olefins are polymerized in the gaseous phase in atleast two independent gas-phase polymerization zones while feeding acatalyst-containing polymer formed in a first polymerization zone to asecond polymerization zone. One type of gas phase reactor is disclosedin U.S. Pat. Nos. 5,352,749, 4,588,790 and 5,436,304, each of which isincorporated by reference in its entirety herein.

In embodiments having multiple reactors, various types of reactors thatmay additionally be included in system 100 may comprise loop slurrypolymerization reactors. Such reactors may have a loop configuration,such as the configuration of the loop slurry polymerization reactor 110of FIG. 1.

In embodiments having multiple reactors, various types of reactors thatmay additionally be included in system 100 may comprise high pressurereactors. High pressure reactors may comprise autoclave or tubularreactors. Tubular reactors may have several zones where fresh monomer(optionally, comonomer), initiators, or catalysts may be added. Monomer(optionally, comonomer) may be entrained in an inert gaseous stream andintroduced at one zone of the reactor. Initiators, catalysts, and/orcatalyst components may be entrained in a gaseous stream and introducedat another zone of the reactor. The gas streams may be intermixed forpolymerization. Heat and pressure may be employed appropriately toobtain optimal polymerization reaction conditions.

In embodiments having multiple reactors, various types of reactors thatmay additionally be included in system 100 may comprise a solutionpolymerization reactor wherein the monomer (optionally, comonomer) maybe contacted with the catalyst composition by suitable stirring or othermeans. A carrier comprising an inert organic diluent or excess monomer(optionally, comonomer) may be employed. If desired, the monomer and/oroptional comonomer may be brought in the vapor phase into contact withthe catalytic reaction product, in the presence or absence of liquidmaterial. The polymerization zone is maintained at temperatures andpressures that will result in the formation of a solution of the polymerin a reaction medium. Agitation may be employed to obtain bettertemperature control and to maintain uniform polymerization mixturesthroughout the polymerization zone. Adequate means are utilized fordissipating the exothermic heat of polymerization.

Conditions of a polymerization reactor, e.g., loop slurry polymerizationreactor 110, which may be chosen and even controlled for polymerizationefficiency and to provide resin properties include temperature, pressureand the concentrations of various reactants. Polymerization temperaturecan affect catalyst productivity, polymer molecular weight and molecularweight distribution. Suitable polymerization temperature may be anytemperature below the de-polymerization temperature according to theGibbs Free energy equation. Typically this includes from about 60° C. toabout 280° C., for example, and from about 70° C. to about 110° C.,depending upon the type of polymerization reactor.

Suitable pressures will also vary according to the reactor andpolymerization type. The pressure for liquid phase polymerizations in aloop reactor such as loop slurry polymerization reactor 110 is typicallyless than 1,000 psig, for example, about 650 psig. Pressure for gasphase polymerization is usually at about 200 to 500 psig. High pressurepolymerization in tubular or autoclave reactors is generally run atabout 20,000 to 75,000 psig. Polymerization reactors can also beoperated in a supercritical region occurring at generally highertemperatures and pressures. Operation above the critical point of apressure/temperature diagram (supercritical phase) may offer advantages.In an embodiment, polymerization may occur in an environment having asuitable combination of temperature and pressure. For example,polymerization may occur at a pressure in a range of about 400 psi toabout 1,000 psi; alternatively, about 550 psi to about 650 psi,alternatively, about 600 psi to about 625 psi; and a temperature in arange of about 150° F. to about 230° F., alternatively, from about 195°F. to about 220° F.

The concentration of various reactants can be controlled to producesolid polymer with certain physical and mechanical properties. Theproposed end-use product that will be formed by the solid polymer andthe method of forming that product determines the desired properties.Mechanical properties include tensile, flexural, impact, creep, stressrelaxation and hardness tests. Physical properties include density,molecular weight, molecular weight distribution, melting temperature,glass transition temperature, temperature melt of crystallization,density, stereoregularity, crack growth, long chain branching andrheological measurements.

The concentrations and/or partial pressures of monomer, comonomer,hydrogen, co-catalyst, modifiers, and electron donors are important inproducing these resin properties. Comonomer may be used to controlproduct density. Hydrogen may be used to control product molecularweight. Cocatalysts can be used to alkylate, scavenge poisons andcontrol molecular weight. Activator-support can be used to activate andsupport the catalyst. Modifiers can be used to control productproperties and electron donors affect stereoregularity, the molecularweight distribution, or molecular weight. In addition, the concentrationof poisons is minimized because poisons impact the reactions and productproperties.

Polymerization reaction components of the reactor(s) disclosed herein(e.g., loop slurry polymerization reactor 110) may include olefinmonomers (e.g., ethylene) and comonomers (e.g., hexene), diluent (e.g.,isobutane, hexane, propane, or combinations thereof), molecular weightcontrol agents (e.g., hydrogen), and any other desired co-reactants oradditives. Polymerization reaction components may additionally include acatalyst, and optionally, a co-catalyst. Suitable catalyst forpolymerizing the monomers and any comonomers may include, but is notlimited to a catalyst(s) and, optionally, a co-catalyst(s) and/or apromoter(s). Nonlimiting examples of suitable catalyst systems includeZiegler Natta catalysts, Ziegler catalysts, chromium catalysts, chromiumoxide catalysts, chromocene catalysts, metallocene catalysts, nickelcatalysts, or combinations thereof. Nonlimiting examples of co-catalystinclude triethylboron, methyl aluminoxane, alkyls such astriethylaluminum, or combinations thereof. Suitable activator-supportsmay comprise solid super acid compounds. Catalyst systems suitable foruse in this disclosure have been described, for example, in U.S. Pat.No. 7,619,047 and U.S. Patent Application Publication Nos. 2007/0197374,2009/0004417, 2010/0029872, 2006/0094590, and 2010/0041842, each ofwhich is incorporated by reference herein in its entirety.

The reaction components may be introduced to an interior of the loopslurry polymerization reactor 110 via inlets or conduits at specifiedlocations, such as feed line 102. Any combination of the reactioncomponents identified above (and others known to those skilled in theart), together with any catalyst and/or co-catalyst described herein,may form a suspension, i.e., a slurry, that circulates through the loopformed by the loop slurry polymerization reactor 110.

The slurry may circulate through the loop slurry polymerization reactor110, and monomers (and optionally, comonomers) may polymerize to form apolymerization product. The polymerization product may comprise apolymerization product slurry, a product mixture, or combinationsthereof.

In embodiments, the polymerization product slurry may comprise solidpolymer and a liquid phase of a diluent. In an embodiment, thepolymerization product slurry may comprise unreacted monomer and/orunreacted comonomer in a liquid phase. In additional or alternativeembodiments, the polymerization product slurry may generally comprisevarious solids, semi-solids, volatile and nonvolatile liquids, orcombinations thereof. In an embodiment, the polymerization productslurry may comprise one or more of hydrogen, nitrogen, methane,ethylene, ethane, propylene, propane, butane, isobutane, pentane,hexane, hexene-1 and heavier hydrocarbons. In an embodiment, ethylenemay be present in a range of from about 0.1% to about 15%,alternatively, from about 1.5% to about 5%, alternatively, about 2% toabout 4% by total weight of the liquid in the product line. Ethane maybe present in a range of from about 0.001% to about 4%, alternatively,from about 0.2% to about 0.5% by total weight of the material in theproduct line. Isobutane may be present in a range from about 80% toabout 98%, alternatively, from about 92% to about 96%, alternatively,about 95% by total weight of the material in the product line.

In embodiments, the product mixture may comprise the solid polymer and avapor phase of at least a portion of the diluent. In additional oralternative embodiments, the mixture may comprise unreacted, gaseousmonomers or optional comonomers (e.g., unreacted ethylene monomers,unreacted butene-1 monomers), gaseous waste products, gaseouscontaminants, or combinations thereof. As used herein, an “unreactedmonomer,” for example, ethylene, refers to a monomer that was introducedinto a polymerization reactor during a polymerization reaction but wasnot incorporated into a polymer. As used herein, an “unreactedcomonomer,” for example, butene-1, refers to a comonomer that wasintroduced into a polymerization reactor during a polymerizationreaction but was not incorporated into a polymer. Such gaseous phaseproduct mixtures may be present when gas phase reactors are used inplace of or in addition to a loop slurry reactor.

In embodiments, the solid polymer may comprise a homopolymer, acopolymer, or combinations thereof. The homopolymer and/or the polymersof the copolymer may comprise a multimodal (e.g., a bimodal) polymer(e.g., polyethylene). For example, the solid polymer may comprise both arelatively high molecular weight, low density (HMWLD) polyethylenepolymer component and a relatively low molecular weight, high density(LMWHD) polyethylene polymer component. Various types of suitablepolymers may be characterized as having a various densities. Forexample, a Type I may be characterized as having a density in a range offrom about 0.910 g/cm³ to about 0.925 g/cm³, alternatively, a Type IImay be characterized as having a density from about 0.926 g/cm³ to about0.940 g/cm³, alternatively, a Type III may be characterized as having adensity from about 0.941 g/cm³ to about 0.959 g/cm³, alternatively, aType IV may be characterized as having a density of greater than about0.960 g/cm³. The solid polymer may comprise other polyolefin polymers.

The polymerization product (e.g., polymerization product slurry) may bewithdrawn from one or more reactors present in system 100, e.g., theloop slurry polymerization reactor 110, via first line 120. Thewithdrawn polymerization product may be conveyed through the first line120 to the second line 130. Collectively, lines 120 and 130 may bereferred to as a flashline between reactor 110 and separation vessel140, wherein a portion, substantially all, or all (e.g., 100%) of liquidphase components present in the polymerization product are converted togas phase components. The polymerization product may be conveyed throughthe second line 130 to the separation vessel 140. In embodiments, thesecond line 130 may be downstream of the first line 120. In embodiments,the first line may have an inner diameter of about 1 inch to about 8inches, and the second line 130 may have an inner diameter of about 2inches to about 10 inches. For example, at least a portion of the secondline 130 may have an inner diameter in a range from about 2 inches toabout 10 inches which is greater than an inner diameter of the firstline 120 in a range from about 1 inch to about 8 inches. In additionalembodiments, the inner diameter of the second line 130 may change (e.g.,increase) along the length of the second line 130.

In an embodiment, a polymerization product slurry in the polymerizationproduct may convert to an at least partial gas phase product mixture inthe first line 120, the second line 130, or combinations thereof. Thus,in embodiments, the polymerization product conveyed through lines 120and 130 may be in the form of a liquid polymerization product slurry(e.g., a slurry of solid polymer and liquid phase diluent and/orunreacted monomer/comonomer), a gas phase product mixture (e.g., solidpolymer and gas phase diluent and/or unreacted monomer/comonomer), orcombinations thereof (e.g., a three-phase mixture of liquid and gaseousdiluent and/or unreacted monomer/comonomer and solid polymer), and theform of the polymerization product may be a function of the conditions(e.g., temperature and pressure) present at a given location in lines120 and 130.

In embodiments, a first pressure differential may be associated with thefirst line 120, and a second pressure differential may be associatedwith the second line 130. The withdrawn polymerization product may beconveyed to separation vessel 140 via the first pressure different andsecond pressure differential, with the withdrawn polymerization productflowing through the first pressure differential before flowing throughthe second pressure differential.

The first pressure differential of first line 120 may be characterizedby a difference in pressure (e.g., a drop in pressure) between P₀ andP₁, and the second pressure differential of the second line 130 may becharacterized by a difference in pressure (e.g., a drop in pressure)between P₁ and P₂. In an embodiment, the difference in pressure betweenP₀ and P₁ may be associated with a continuous take-off valve, as isdescribed in detail for the embodiment of FIG. 2. In an embodiment, thedifference in pressure between P₁ and P₂ may be associated with theflashline heater, as is described in detail for the embodiment of FIG.2.

In an embodiment, the first pressure differential (e.g., a drop inpressure between P₀ and P₁) of the first line 120 may be less than thesecond pressure differential (e.g., a drop in pressure between P₁ andP₂) of the second line 130. In an embodiment, the first pressuredifferential may have a drop in pressure between about 5% to about 50%of a total pressure differential (e.g., the sum of the first pressuredifferential and the second pressure differential) between the looppolymerization reactor 110 and the separation vessel 140, and the secondpressure differential may have a drop in pressure between about 50% toabout 95% of the total pressure differential between the looppolymerization reactor 110 and the separation vessel 140. In analternative embodiment, the first pressure differential may have a dropin pressure greater than about 40% and less than about 50% of a totalpressure differential between the loop polymerization reactor 110 andthe separation vessel 140, and the second pressure differential may havea drop in pressure greater than about 50% and less than about 60% of thetotal pressure differential between the loop polymerization reactor 110and the separation vessel 140. In an alternative embodiment, the firstpressure differential may have a drop in pressure greater than about 40%and less than about 45% of a total pressure differential between theloop polymerization reactor 110 and the separation vessel 140, and thesecond pressure differential may have a drop in pressure greater thanabout 55% and less than 60% of the total pressure differential betweenthe loop polymerization reactor 110 and the separation vessel 140.

In an embodiment, the first pressure differential (e.g., a drop inpressure between P₀ and P₁) of the first line 120 may be greater thanthe second pressure differential (e.g., a drop in pressure between P₁and P₂) of the second line 130. In an embodiment, the first pressuredifferential may have a drop in pressure between about 50% to about 95%of a total pressure differential (e.g., the sum of the first pressuredifferential and the second pressure differential) between the looppolymerization reactor 110 and the separation vessel 140, and the secondpressure differential may have a drop in pressure between about 5% toabout 50% of the total pressure differential between the looppolymerization reactor 110 and the separation vessel 140. In analternative embodiment, the first pressure differential may have a dropin pressure greater than about 50% and less than about 60% of a totalpressure differential between the loop polymerization reactor 110 andthe separation vessel 140, and the second pressure differential may havea drop in pressure greater than about 40% and less than about 50% of thetotal pressure differential between the loop polymerization reactor 110and the separation vessel 140. In an alternative embodiment, the firstpressure differential may have a drop in pressure greater than about 55%and less than about 60% of a total pressure differential between theloop polymerization reactor 110 and the separation vessel 140, and thesecond pressure differential may have a drop in pressure greater thanabout 40% and less than 45% of the total pressure differential betweenthe loop polymerization reactor 110 and the separation vessel 140.

In an embodiment, the drop in pressure of the first pressuredifferential is from a pressure (e.g., less than 1,000 psig) of the loopslurry polymerization reactor 110 to a pressure less than the pressureof the loop slurry polymerization reactor 110. In embodiments, the firstpressure differential of the first line 120 may be configured such thatthe second pressure differential of the second line 130 may bemaintained above a minimum value. In an embodiment, the second pressuredifferential may be adequate such that an inner diameter of the secondline 130 may be increased at least once along the second line 130.

In an embodiment, polymer product withdrawn from the loop slurrypolymerization reactor 110 may convey through the first line 120 andsecond line 130 via the total pressure differential (i.e., the sum ofthe first and second pressure differentials) between the operatingpressure of the loop slurry polymerization reactor 110 and theseparation vessel 140. In an embodiment, the polymerization product(e.g., polymerization product slurry, mixture, or combinations thereof)may convey through the first line 120 (e.g., comprising a continuoustake-off valve, as described in detail for the embodiment in FIG. 2) toyield an at least partial gas phase mixture (e.g., mixture of gas phasediluent and/or unreacted monomer/comonomer and solid polymer). Forexample, the polymerization product slurry may be conveyed through thefirst line 120 comprising a continuous take-off valve to yield a mixture(e.g., a gas phase mixture) comprising a vapor phase, or gas phase,which exits the continuous take-off valve. The vapor phase of themixture may comprise greater than about 0%, 1%, 2%, 3%, 4%, 5%, or moreby weight of the mixture in the first line 120 (e.g., the mixture whichexits the continuous take-off valve of the first line 120). Further, theconcentration of the vapor phase of the mixture exiting the continuoustake-off valve may increase as the mixture is conveyed through theremainder of the first line 120 and subsequently through the second line130.

In an embodiment, a valve is present at the interface between the firstline 120 and the second line 130. In alternative embodiments, thepolymerization product may convey through the first line 120 and intothe second line 130, where an at least partial gas phase mixture isyielded in the second line 130 (e.g., via a flashline heater, asdescribed in detail for the embodiment in FIG. 2). The position of theseparation vessel 140 relative to the loop slurry polymerization reactor110 may be adjusted in order to transfer withdrawn polymer product viathe total pressure differential, for example, to minimize or reduce theequipment dedicated to polymer product conveyance, to volatilize allliquid in the polymer product, or combinations thereof. In anembodiment, the total pressure differential is the sole means forconveying polymer product between the loop slurry polymerization reactor110 and separation vessel 140.

The size of the total pressure differential may impact the distance thepolymer may be transferred between the loop slurry polymerizationreactor 110 and separation vessel 140. In an embodiment, the totalpressure differential may comprises a drop in pressure from equal to orless to about 1,500 psig in the reactor 110 to equal to or greater thanabout 50 psig in the separation vessel 140; alternatively, a drop fromequal to or less than about 1,000 psig to equal to or greater than about100 psig; alternatively, a drop from equal to or less than about 650psig to greater than or equal to about 135 psig. In an embodiment, thesolid polymer comprises polyethylene, the diluent comprises isobutane,and the total pressure differential comprises a drop in pressure fromabout 650 psig to about 150 psig. In an embodiment, the solid polymercomprises polypropylene, the diluent comprises isobutane, and the totalpressure differential comprises a drop in pressure from about 650 psigto about 225 psig, alternatively, from about 650 psig to about 240 psig.System capacity also impacts the ability of the total pressuredifferential to transfer pounds of polymer over a distance per year. Inan embodiment, the total pressure differential may transfer from about100 million to about 2 billion pounds per year; alternatively, fromabout 500 million to about 1.8 billion pounds per year; alternatively,from about 1 to about 1.5 billion pounds per year.

The first and second pressure differentials of the first line 120 andsecond line 130 may convey or transfer the polymerization productthrough the first line 120 and second line 130 at one or morevelocities. For example, the polymerization product may transfer throughthe first line 120 and/or the second line 130 at a velocity (e.g., anaverage velocity) of between about 25 ft/s (about 7.6 m/s) and about 270ft/s (about 82.4 m/s). In embodiments, the velocity of thepolymerization product through the first line 120 is different than thevelocity of the polymerization product through the second line 130. Inembodiments, the polymerization product may experience more than onevelocity (e.g., before a continuous take-off valve, through a continuoustake-off valve, and after a continuous take-off valve) as thepolymerization product transfers through the first line 120. Inembodiments, the polymerization product may experience more than onevelocity (e.g., different velocities for one or more segments of aflashline heater, as described in FIGS. 2 and 3) as the polymerizationproduct transfers through the second line 130. In an embodiment, thepolymerization product (e.g., polymerization product slurry, productmixture, or combinations thereof) may be conveyed through the first line120, the second line 130, or both, such that the polymerization product(e.g., polymerization product slurry, product mixture, or combinationsthereof) has a Froude number (discussed in detail for the embodiment inFIG. 2) at one or more points in the first line 120, second line 130, orboth, in a range from about 5 to about 100.

The first and second pressure differentials of the first and secondlines 120 and 130 may generate a cooling effect on the polymerizationproduct which may counteract a desired volatization of liquid in thepolymerization product. In an embodiment, polymerization product in thefirst line 120, second line 130, or both, may be heated to maintain orraise the temperature of the polymer product during transfertherethrough. In an embodiment, a flashline heater, e.g., steam or hotwater jackets, (discussed in detail for the embodiments shown in FIGS. 2and 3) may heat of the first line 120, second line 130, or both. Theheating may be controlled so that it does not cause the polymer productto reach the melting or softening temperature. In an embodiment, thesolid polymer comprises polyethylene and the heating results in a solidpolymer temperature of greater than or equal to about 0° F. and lessthan or equal to about 230° F.; alternatively, greater than or equal toabout 0° F. and less than or equal to about 180° F. In an embodiment,the solid polymer comprises polypropylene and the heating results in asolid polymer temperature of greater than or equal to about 0° F. andless than or equal to about 250° F.; alternatively, greater than orequal to about 0° F. and less than or equal to about 220° F.;alternatively, greater than or equal to about 0° F. and less than orequal to about 170° F.

In embodiments, the first pressure differential of the first line 120,the second pressure of the second line 130, the heating of the firstline 120, the heating of the second line 130, or combinations thereofmay vaporize a substantial amount (e.g., at least about 50%, 75%, 90%,95%, 99%, 99.5% or more) of the liquid in the polymerization productprior to delivery to the separation vessel 140. In alternativeembodiments, the first pressure differential of the first line 120, thesecond pressure of the second line 130, the heating of the second line130, or combinations thereof may vaporize substantially all (e.g., atleast about 99%, 99.9%, 99.99%, 99.999%, or 100% by weight volatized) ofthe liquid in the polymerization product prior to delivery to theseparation vessel 140.

A separation vessel 140 may recover solid polymer which is received fromthe second line 130. In one or more of the embodiments disclosed herein,the polymerization product flowing from the second line 130 (forexample, a mixture of solid polymer and at least a portion,substantially all or all of the other components, e.g., diluent and/orunreacted monomer/comonomer, are in a gas phase) may be separated intosolid polymer in line 144 and one or more gases in line 142 inseparation vessel 140.

Any suitable technique may be used to separate the polymerizationproduct into solid polymer and gases. For example, the separation vessel140 may comprise a vapor-liquid separator. Suitable embodiments of avapor-liquid separator may include a distillation column, a flash tank,a filter, a membrane, a reactor, an absorbent, an adsorbent, a molecularsieve, a cyclone, or combinations thereof. In an embodiment, theseparator comprises a flash tank. Not seeking to be bound by theory,such a flash tank may comprise a vessel configured to vaporize and/orremove low vapor pressure components from a high temperature and/or highpressure fluid.

In an embodiment, the separation vessel 140 may be configured such thatpolymerization product from second line 130 may be separated into solidand liquid (e.g., a condensate) phase components in line 144 and a gas(e.g., vapor) phase components in line 142. The liquid or condensate maycomprise solid polymer (e.g., polyethylene) and any liquid phasecomponents such as diluent and/or unreacted monomer/comonomer, and insome embodiments line 144 is a concentrated slurry in comparison to theproduct slurry in lines 120 and 130. The gas or vapor may comprisevolatile solvents, diluent, unreacted monomers and/or optionalcomonomers, waste gases (e.g., secondary reaction products, such ascontaminants and the like), or combinations thereof. The separationsvessel 140 may be configured such that the polymerization productflowing from the second line 130 is flashed by heat, pressure reduction,or combinations thereof such that the enthalpy of the line is increased.This may be accomplished via a heater, a flashline heater, various otheroperations commonly known in the art, or combinations thereof. Forexample, a flash line heater comprising a double pipe may exchange heatby hot water or steam. Such a flashline heater may increase thetemperature of the second line 130 while reducing its pressure.

In an alternative embodiment, the separation vessel 140 may beconfigured such that polymerization product from second line 130 may beseparated into solid polymer in line 144 substantially or completelyfree of any liquid phase components and one or more gases in line 142.Suitable separation techniques include distilling, vaporizing, flashing,filtering, membrane screening, absorbing, adsorbing, cycloning, gravitysettling, or combinations thereof, the polymerization product receivedin separation vessel 140 from the second line 130.

In an embodiment, the separation vessel 140 may operate at a pressure offrom about 50 psig to about 500 psig; alternatively, from about 130 psigto about 190 psig; alternatively, at about 135 psig.

In one or more embodiments, the gas in line 142 may comprise hydrogen,nitrogen, methane, ethylene, ethane, propylene, propane, butane,isobutane, pentane, hexane, hexene-1 and heavier hydrocarbons. In anembodiment, ethylene may be present in a range of from about 0.1% toabout 15%, alternatively, from about 1.5% to about 5%, alternatively,about 2% to about 4% by total weight of the line. Ethane may be presentin a range of from about 0.001% to about 4%, alternatively, from about0.2% to about 0.5% by total weight of the line. Isobutane may be presentin a range from about 80% to about 98%, alternatively, from about 92% toabout 96%, alternatively, about 95% by total weight of the line.

The separation vessel 140 may additionally comprise any equipmentassociated with the separation vessel 140, such as control devices(e.g., a PID controller) and measurement instruments (e.g.,thermocouples), and level control and measurement devices.

In an embodiment, the horizontal distance between the separation vessel140 and the loop slurry polymerization reactor 110 may be adjusted tooptimize layout and cost. In an embodiment, the first and secondpressure differentials transfer the polymer product to separation vessel140 which may be from about 0 to about 3,000 horizontal feet from theloop slurry polymerization reactor 110; alternatively, the separationvessel 140 may be from about 0 to about 1,500 horizontal feet from theloop slurry polymerization reactor 110; alternatively, the separationvessel 140 may be from about 100 to about 1,500 horizontal feet from thereactor 110; alternatively, the separation vessel 140 may be from about100 to about 500 horizontal feet from the reactor 110; alternatively,the separation vessel 140 may be from about 200 to about 500 horizontalfeet from the reactor 110. In various embodiments, the polymer productmay travel a linear distance through first line 120 and second 130 in x,y, and z coordinates, for example through circuitous pipe routing, thatis greater than the horizontal distance, the vertical spacing/distance,or combinations thereof.

FIG. 2 shows a process flow diagram of another embodiment of a system200 for pressure management of a polymerization product in a looppolymerization process. Similar to the embodiment of the system 100 ofFIG. 1, system 200 may comprise a loop slurry polymerization reactor210, a first line 220, a second line 230, and a separation vessel 240,which share the same qualities as those described above for the loopslurry polymerization reactor 110, first line 120, second line 130, andseparation vessel 140 of FIG. 1, except where explained below in thealternative.

In embodiments such as that shown in FIG. 2, the first line 220 of thesystem 200 may comprise a continuous take-off valve (hereinafter “CTOvalve”) 222. In embodiments, various lines may be used to connect theCTO valve 222 in the first line 220. For example, line 224 may connectthe CTO valve 222 with the loop slurry polymerization reactor 210, andline 226 may connect the CTO valve 222 with the second line 230 (e.g.,with the flashline heater 232). In alternative or additionalembodiments, the CTO valve 222 may connect directly or indirectly to theloop slurry polymerization reactor 210. In alternative or additionalembodiments, the CTO valve 222 may connect directly or indirectly to theflashline heater 232. In embodiments, the CTO valve 222 may have adiameter of about 1 inch to about 8 inches.

In embodiments such as that shown in FIG. 2, the second line 230 maycomprise a flashline heater 232. In embodiments, various lines may beused to connect the flashline heater 232 in the second line 230. Forexample, the flashline heater 232 may connect directly to the first line220, and line 266 may connect the flashline heater 232 to the separationvessel 240. In alternative or additional embodiments, the flashlineheater 232 may connect directly or indirectly to the first line 220. Inalternative or additional embodiments, the flashline heater 232 mayconnect directly or indirectly to the separation vessel 240.

As with the embodiment shown in FIG. 1, the system 200 of FIG. 2 mayhave a first pressure differential and a second pressure differential.The first pressure differential may be associated with the first line220 comprising the CTO valve 222, and the second pressure differentialmay be associated with the second line 230 comprising the flashlineheater 232.

In FIG. 2, the first pressure differential of first line 220 may becharacterized by a difference in pressures between any two pressures P₀,P₁, P₂, and P₃. In an embodiment, the difference in pressures betweenany two pressures P₀, P₁, P₂, and P₃ may be characterized as a drop inpressure. In an embodiment, the difference in pressures between P₁ andP₂ may be associated with the CTO valve 222. In an embodiment, thedifference in pressures associated with the CTO valve 222 may depend onthe position (e.g., valve rotation) of the valve, i.e., the degree bywhich the CTO valve 222 is open. For example, the CTO valve 222 may havea valve rotation of about 5°, 10°, 20°, 30°, 40°, 50°, 60°, 70°, 80°,90°, or more.

The second pressure differential of second line 230 may be characterizedby a difference in pressures between any two pressures P₃, P₄, and P₅.In an embodiment, the difference in pressures between any two pressuresP₃, P₄, and P₅ may be characterized as a drop in pressure. In anembodiment, the difference in pressures between P₃ and P₄ may beassociated with the flashline heater 232.

In an embodiment, the difference in pressure between P₁ and P₂ maycomprise a majority of the first pressure differential of first line220. In an additional or alternative embodiment, the difference inpressure between P₀ and P₂ may comprise a majority of the first pressuredifferential of first line 220. In an additional or alternativeembodiment, the difference in pressure between P₁ and P₃ may comprise amajority of the first pressure differential of first line 220. In anembodiment, the difference in pressure between P₃ and P₄ may comprise amajority of the second pressure differential of second line 230. In anadditional or alternative embodiment, the difference in pressure betweenP₃ and P₅ may comprise a majority of the second pressure differential ofsecond line 230. In an additional or alternative embodiment, thedifference in pressure between P₄ and P₅ may comprise a majority of thesecond pressure differential of second line 230.

In an embodiment, the system 200 may further comprise a control system260 for controlling the withdrawal of polymer product from the loopslurry polymerization reactor 210. The control system 260 may control,for example, the CTO valve 222 and/or control and/or measurementinstruments for the loop slurry polymerization reactor 220 (e.g.,sensors of weight percent solids, reactor pressure, supply of feed,fluidized bed height, etc., or combinations thereof). The control system260 may additionally or alternatively monitor and maintain the amount ofpolymer product in the loop slurry polymerization reactor 210 bycontrolling the flow of polymerization product from the reactor 210 tothe separation vessel 260 via the first line 220 and second line 230.The control system 260 may additionally or alternatively monitor lineconditions with sensors 246, e.g., for lines 266, 242, and 244. Thecontrol system 260 may additionally or alternatively monitor andmaintain the level of solid polymer in the separation vessel 240, forexample via one or more sensors 246. In an embodiment, the controlsystem 260 may adjust a flow of polymer product in the first line 220and/or second line 230 via adjustment of the CTO valve 222.

In an embodiment, the CTO valve 222 may comprise a solids-tolerantvalve. In alternative embodiments, the CTO valve 222 may comprise a plugvalve, or a ball valve, such as a Vee-Ball valve. The CTO valve 222 mayhave a flow coefficient, C_(v). The C_(v) of the CTO valve 222 may bematched such that a drop in pressure in the flashline heater 232 ismaximized. In an embodiment, a drop in pressure of the flashline heater232 is adequate to increase an inner diameter of the flashline heater232 at least once, i.e., the flashline heater 232 may have at least twoinner diameters. Generally, the longer the total length of the flashlineheater 232, the larger the value of the C_(v) of the CTO valve 222.Generally, the higher the production rate of solid polymer the largerthe total length may be required for the flashline heater 232.Generally, the lower the density of the solid polymer the larger thetotal length may be required for the flashline heater 232. In anembodiment, the C_(v) of the CTO valve 222 is matched to maximizevaporization of liquids in the flashline heater 232. For example, a CTOvalve 222 having a valve size of one inch may have a C_(v) in a range ofabout 0.0401 corresponding to a valve rotation of about 10° to about32.1 corresponding to a valve rotation of about 90′; alternatively, aCTO valve 222 having a valve size of 1.5 inches may have a C_(v) in arange of about 0.288 corresponding to a valve rotation of about 10° toabout 72.1 corresponding to a valve rotation of about 90′;alternatively, a CTO valve 222 having a valve size of two inches mayhave a C_(v) in a range of about 0.158 corresponding to a valve rotationof about 10° to about 125 corresponding to a valve rotation of about90′; and so on.

As shown in FIG. 2, the flashline heater 232 may comprise a plurality ofsegments 234 connected in series. One or more of the plurality ofsegments 234 of the flashline heater 232 may comprise a segment set. Inembodiments, a segment set may comprise a group of the segments 234 ofthe flashline heater 232 which are connected in series and which mayshare a common parameter such as inner diameter, whether the segmentsare heated, or combinations thereof; alternatively, a single segment ofthe plurality of segments 234 may comprise a segment set which has aparameter different than other segments and/or segment sets. Forexample, Table 2 shows data for the flashline heater of Example 1 havingtwenty-nine segments, where segment set 1 comprises segments 1 to 6(which are not heated), segment set 2 comprises segments 7 to 26 (whichare heated) and segment set 3 comprises segments 27 to 29 (which are notheated). As another example, Table 4 shows data for a flashline heaterof Example 2 having 29 segments, where segment set 1 comprises segments1 to 6 (which are not heated and have an inner diameter of 2.067inches), segment set 2 comprises segments 7 to 14 (which are heated andhave an inner diameter of 2.469 inches), segment set 3 comprisessegments 15 to 21 (which are heated and have an inner diameter of 3.068inches), segment set 4 comprises segments 22 to 26 (which are heated andhave an inner diameter of 4.026 inches), and segment set 5 comprisessegments 27 to 29 (which are not heated and have an inner diameter of4.026 inches). In additional or alternative embodiments, the commonparameter of segments in a segment set may comprise outer diameter,segment length, segment material, or combinations thereof. In otherembodiments, segment sets may be determined by inner diameter only;alternatively, outer diameter only, alternatively, segment length only.

The flashline heater 232 may be generally sized and configured toreceive polymerization product from the first line 230 and vaporize atleast a portion of the liquid in the polymerization product (e.g.,liquid of polymerization product slurry) to convert at least a portionof the polymerization product to a polymer solids and gas phase mixture.In an embodiment, a liquid of the polymerization product may comprise afirst portion not entrained within solid polymer and a second portionentrained within the solid polymer. In embodiments, the flashline heater332 may vaporize substantially all (e.g., at least about 99%, 99.9%,99.99%, 99.999%, or 100% by weight volatized) of the first portion ofthe liquid (i.e., the portion not entrained within the solid polymer) inthe polymerization product prior to delivery to the separation vessel240. In embodiments, the flashline heater 332 may vaporize a substantialamount (e.g., at least about 75%, 90%, 95%, 99%, 99.5% or more) of thesecond portion of the liquid (i.e., the portion entrained within thesolid polymer) in the polymerization product prior to delivery to theseparation vessel 240.

Generally, the flashline heater 232 may be configured such that thetravel time of the solid polymer through the flashline heater 232 is atleast or greater than about 7.5 seconds; alternatively, greater thanabout 8 second; alternatively, greater than about 8.5 seconds;alternatively, greater than about 9 seconds; alternatively, greater thanabout 9.5 seconds; alternatively, greater than about 10 seconds;alternatively, greater than about 10.5 seconds; alternatively, greaterthan about 11 seconds. In embodiments, the flashline heater 232 may beconfigured such that the travel time of the solid polymer through theflashline heater 232 is about 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5,or more seconds. As the polymerization product flows through theflashline heater 232, the temperature of its various components mayapproach equilibration. For example, the temperature between thevaporized first portion of the liquid, the solid polymer, and the secondportion of the liquid may become substantially equilibrated or have atemperature difference of less than about 10° F.

Generally, at least one of the segments 234 may have an inner diametergreater than an inner diameter of a preceding segment. In an embodiment,at least one of the segments 234 may have an inner diameter greater thana diameter of the CTO valve 222. The inner diameters of the segments 234may increase along the length of the flashline heater 232 as shown inFIG. 2. For example, segments of segment set 237 have an inner diametergreater than preceding segments of segment set 236, segments of segmentset 238 have an inner diameter greater than preceding segments ofsegment sets 237 and 236, and segments of segment set 239 have an innerdiameter greater than preceding segments of segment sets 238, 237, and236. In embodiments, the flashline heater 232 may have an inner diameterof about 2 inches to about 10 inches. In embodiments, the segments 234may have an inner diameter of about 2 inches to about 10 inches. Inembodiments, each of the segments 234 may have an outer diameter betweenabout 4 and about 16 inches (e.g., about 4 inches, 5 inches, 6 inches, 7inches, 8 inches, inches, 9 inches, 10 inches, 11 inches, 12 inches, 13inches, 14 inches, 15 inches, or 16 inches). Further, the segments 234may each have a length that is between about 5 feet and about 100 feet(e.g., about 10 feet, 15 feet, 20 feet, 25 feet, 30 feet, 35 feet, 40feet or greater). Each of segments 234 may have the same or differentlength as other segments, and the length of each segment 234 may dependon the particular number of segments 234 employed and the total lengthof the flashline heater 232 in a given implementation. The flashlineheater 232 may have a total length greater than about 100 feet;alternatively, greater than about 200 feet; alternatively, greater thanabout 300 feet; alternatively, greater than about 400 feet;alternatively, greater than about 500 feet; alternatively, greater thanabout 600 feet; alternatively, greater than about 700. In an embodiment,the flashline heater 232 may have a total length of about 560 feet;alternatively, about 630 feet; alternatively, about 700 feet. Inembodiments, the flashline heater 232 may have a length and one or moreinner diameters such that the flashline heater 232 provides thepolymerization product (e.g., polymerization product slurry, productmixture, or combinations thereof) a residence time of at least orgreater than about 7.5; alternatively, greater than about 8 second;alternatively, greater than about 8.5 seconds; alternatively, greaterthan about 9 seconds; alternatively, greater than about 9.5 seconds;alternatively, greater than about 10 seconds; alternatively, greaterthan about 10.5 seconds; alternatively, greater than about 11 seconds.In embodiments, the flashline heater 232 may have a length and one ormore inner diameters such that the flashline heater 232 provides thepolymerization product a residence time of about 7.5, 8, 8.5, 9, 9.5,10, 10.5, 11, 11.5, or more seconds.

In embodiments where a polymerization product is conveyed through atleast a portion of the flashline heater 232 (e.g., a segment 234, aportion of a segment 234, two or more segments, a segment set, a portionof a segment set, or combinations thereof), the product stream may havea Froude number in a range from about 5 to about 100; alternatively,from about 10 to about 55; alternatively, from about 10 to about 50;alternatively, from about 15 to about 55; alternatively, from about 20to about 70; alternatively, from about 20 to about 40; alternatively,from about 15 to about 30. The Froude number as used herein is definedas a dimensionless parameter indicative of the balance between thesuspension and settling tendencies of particles in the polymerizationproduct, e.g., the polymerization product slurry. It provides a relativemeasure of the momentum transfer process to the pipe wall from particlescompared to the fluid. Lower values of the Froude number indicatestronger particle-wall (relative to fluid-wall) interactions. The Froudenumber (Fr) may be defined using the following equation:

Fr=V/(D*g)^(0.5)

where V is the average velocity (units of ft/s) of the polymerizationproduct (e.g., polymerization product slurry, solid/gas phase mixture,combinations thereof, or components thereof), g is the gravitationalconstant (32.2 ft/s²), and D is the internal pipe diameter (units offt). The Froude number may be used to describe at least a portion of thepolymerization product in at least a portion a segment of the flashlineheater 232, in a combination of segments of the flashline heater 232, insegment sets, combinations thereof, or across the entire flashlineheater 232.

In embodiments, the average velocity in stream 230 may be in a range ofabout 25 ft/s (about 7.6 m/s) to about 270 ft/s (about 82.4 m/s);alternatively, in a range of about 40 ft/s (about 12.2 m/s) to about 160ft/s (about 48.8 m/s). In an embodiment, the velocity of thepolymerization product may be below a sonic velocity of the polymerproduct.

FIG. 3 shows a cross-sectional view of an embodiment of a portion of theflashline heater 332, taken along sight line 3-3 of FIG. 2. The portionof the flashline heater 332 has length “l”. As shown in FIG. 3, apolymerization product 322 may enter the portion of the flashline heater332. At least a portion of the liquid components in polymerizationproduct 322 may convert to gas phase, thereby yielding a mixed phaseproduct stream 366 (e.g., polymer solids, gas phase components, and insome instances, remaining liquid components) which exits the portion ofthe flashline heater 332. The characteristics (e.g., amount of gasand/or liquid phase of various components) of the product stream 366delivered to the separation vessel 340 may depend on many factorsincluding but not limited to a length “l” of the portion of theflashline heater 332, a diameter “d_(o)” of an outer conduit 370 of theflashline heater 332, an internal diameter “d_(i)” of the segments 334of the flashline heater 332, the velocity of the product stream in theflashline heater 332, the velocity of the polymerization product in theflashline heater 332 in relation to the take-off velocity of thepolymerization product 322, the chemical nature of the components withinthe polymerization product 322, the amount of flash occurring upstreamfrom the flashline heater 332 (e.g., in CTO valve 222), or combinationsthereof.

To affect the volatilization of the liquid within the polymerizationproduct 322, the flashline heater 332 may also include a plurality ofsegments 335 forming an outer conduit 370, which may wrap around atleast a portion of one or more of the segments 334. The segments 335 maybe configured to facilitate a flow of a warming medium through a portionor the entire outer conduit 370. The segments 335 may have the same ordiffering diameters and/or lengths as one another. In embodiments, thesegments 335 may have correspondingly same or differing diameters and/orlengths as the segments 334 which they wrap around.

In an embodiment, the warming medium that flows through the segments 335may allow the flashline heater 332 to heat the polymerization product322 through, for example, length t, one or more sections (e.g., segmentsets—contiguous or non-contiguous) of the flashline heater 332, orthroughout the entire length of the flashline heater 332. That is, thesegments 335 of the flashline heater 332 may increase, decrease, ormaintain the temperature of the polymerization product 322 as it flowsthrough segments 334, which may allow for control of the heating rateand/or resulting temperature of the solid polymer as the polymerizationproduct 322 flows through the flashline heater 332, as portions of theliquid components of the polymerization product 322 convert to gasphase, as the mixed phase product stream 366 exits the flashline 332, orcombinations thereof. During operation, the warming medium may flowthrough one or more segments 335 of the outer conduit 370, whichindirectly heats the polymerization product 322 as the polymerizationproduct 322 flows through the segments 334. In other words, the warmingmedium flowing through one segment 335 may be substantially separatedfrom the warming medium flowing through another segment 335, such thateach segment 335 may be separated from the other, thereby allowingindependent control of heating across one or more segments.Alternatively or additionally, two or more segments 335 may share a flowof warming medium. For example, the two or more segments 335 may share asingle inlet and outlet. In some embodiments, the warming medium may bewarmed coolant from the cooling jackets of the polymerization reactor(e.g., jackets 113 of FIG. 1), steam or steam condensate, hot oil,another heating source such as heat generated by electrical resistanceheaters, or combinations thereof.

In embodiments, the flashline heater 332 may allow warming medium toflow through any one or a combination of the segments 335. For example,the heating medium may flow through a first set 306 of segments 335 butnot through a second set 308 of segments 335, or any similar flow ortemperature scheme, such as through every third segment, or throughthree segments and not through a fourth, and so on. For example, in theillustrated embodiment, the warming medium may flow into a respectiveinlet 310 and out of a respective outlet 312 of each one of the segments335. Alternatively, combinations of segments 335 may have a common inletand/or a common outlet. In one implementation, when the warming mediumflows through the first set 306 of segments 335 but not the second set308, it may initially warm the polymerization product 322 such thatsubstantially all of the liquid within the polymerization product 322 isvaporized, followed by a period of cooling or temperature maintenance.Whether the second set 308 of segments 335 may be used to provide heatmay depend on the measured levels of liquid (e.g., diluent) entrainedwithin the solid polymer, the desired specifications of the solidpolymer, desired solid polymer temperature, or combinations thereof.However, it should be noted that, in embodiments where the flashlineheater 332 is configured to substantially continuously heat thepolymerization product 322 along a length of greater than about 700feet, the solid polymer may begin to melt, which may cause difficulty infurther processing. By controlling the amount of warming fluid flowingthrough each segment 335 or combination of segment sets (such as 306 and308), an operator and/or controller may be able to adjust thetemperature of the polymerization product to a desired level. In oneembodiment, the temperature difference between the vapor and solidpolymer in the polymer product stream 366 exiting the flashline heater332 may be substantially negligible or the temperature of the solidpolymer may approach about within 40° F., 20° F., 10° F., 5° F., or 1°F. of the temperature of the vapor. Further, the polymer product stream366 may approach a thermal equilibrium, such that substantially all ofthe liquid present (e.g., liquid entrained in the solid polymer), thevapor and the solid polymer each have a temperature that differ from oneanother by no more than 1° F.

In an embodiment, the flashline heater 332 may reduce a boiling point ofliquid in the polymerization product at a given pressure. In such anembodiment, the liquid may more readily volatize in the flashline heater332.

In additional or alternative embodiments, the volatilization and/orthermal equilibration may at least partially depend on the total lengthof the flashline heater 332. For example, the total length of theflashline heater 332 may at least partially determine the temperature ofthe product stream 366 as well as the extent of entrained liquidremaining within the solid polymer. In a general sense, the total lengthof the flashline heater 332 may at least partially determine how muchtime the polymerization product may spend in heated areas, in cooledareas, in areas of high and/or low pressure, and so on. In this way, thetotal length of the flashline heater 332 may at least partiallydetermine the amount of time between full vaporization of liquids notassociated or entrained within the solid polymer of the polymerizationproduct 322 and the delivery of the product stream 366 exiting theflashline heater to the separation vessel 340. Therefore, it should benoted that in some configurations, such as those with a substantiallyconstant diameter and temperature, that as the total length of theflashline heater 332 increases, so may the transit time of thepolymerization product 322 through the flashline heater 332 and thelikelihood that the first portion of liquid is completely volatized andthe second portion of liquid has been substantially volatilized.

While the total length of the flashline heater 332 may at leastpartially determine the transit time of the polymerization product 322,the diameters d_(i) and d_(o) may at least partially determine the rateat which the liquids within the polymerization product 322 volatilize.Therefore, the total length and diameters d_(i) and d_(o) of theflashline heater 332 may have a synergistic effect in determining thecharacteristics of the product stream 366 exiting the flashline heaterand delivered to the separation vessel 340. Therefore, it should benoted that an increase in both the total length and the internaldiameter d_(i) relative to conventional dimensions may greatly increasethe probability of full vaporization of liquids and/or temperatureequilibration for the vapor, liquids, solid polymer, or combinationsthereof.

In embodiments, the inner diameter d_(i) of segments 334 may changealong the length of the flashline heater 332. Therefore, thepolymerization product 322 may experience changing pressure proportionalto the diameter change as it progresses through the flashline heater332. Temperature and/or pressure changes may be substantially static(e.g., unchanging throughout the total length of the flashline heater332 in time) or may be dynamic (e.g., changing throughout the totallength of the flashline heater 332 in time). That is, the segments 334may have different or the same heating temperatures, different or thesame pressures, or any combination of these. The first portion of theliquid of the polymerization product 322 (the portion not entrainedwithin the solid polymer) may be substantially totally volatilized(e.g., at least about 99%, 99.9%, 99.99%, 99.999%, or 100% by weightvolatized) with sufficient remaining transit time to allow the secondportion to substantially volatilize (e.g., at least about 75%, 90%, 95%,99%, or 99.5% by weight of the second portion of liquid is volatilized),or at least to reach a thermal equilibrium with the solid polymer andvapor within the product stream 366 exiting the flashline heater 332.Again, when the phases of the product stream 366 have reached thermalequilibrium, the phases will differ in temperature by no more than about1° F.

To reach substantial vaporization and/or thermal equilibrium, inaccordance with present embodiments, the polymerization product 322 mayflow through the flashline heater 332 through the segments 334 havinginternal diameter d_(i). Substantially concurrently, the polymerizationproduct 322 is heated by a warming fluid within the outer conduit 370having the diameter d_(o), which may surrounds at least a portion of oneor more of segments 334. According to the present approaches, either orboth of these diameters may impact the rate at which liquids within thepolymerization product 322 volatilize. For example, in some embodiments,the inner diameter d_(i) may be inversely proportional to the pressurewithin the flashline heater 332. That is, as the diameter d_(i)increases, the pressure acting on the polymerization product 322 maydecrease, which may allow an increased rate of volatilization of theliquids. Also, as the d_(i) increases, the velocity decreases andprovides additional residence time for volatization. Accordingly, insome embodiments, the internal diameter d_(i) of the segments 334 isincreased relative to conventional designs, such as to diameters of atleast 2, 3, 4, 5, 6, 7, or 8 inches, or more.

An increase in the diameter d_(o) may also increase the rate ofvolatilization of the liquids within the polymerization product 322. Forexample, the diameter d_(o) may define the amount of warming fluidavailable to the outer surface of the segments 334 for indirectlyheating the polymerization product 322. While the exchange of heatbetween the warming medium and the polymerization product 322 may besubstantially limited by the outer and inner surface areas of thesegments 334, it should be noted that as the diameter d_(o) of the outerconduit 370 increases, so may the amount of warming medium available forheat exchange. Accordingly, as the amount of warming medium within theouter conduit 370 increases, heat transfer to the polymerization product322 may have a minimized impact on the average temperature of thewarming medium within the outer conduit 370. Therefore, by increasingthe diameter d_(o) relative to diameter d_(i), more efficient heating ofthe polymerization product 322, and therefore volatilization of theliquids within the polymerization product 322, may be realized.

It should be noted, in light of the present discussion, that thediameter d_(o) of the outer conduit 370, the diameter d_(i) of one ormore segments 334, the total length of the flashline heater 332, andtheir interrelation may at least partially determine the relative timesof conversion for the liquid(s) of the polymerization product 322entering the flashline heater to convert to vapor in product stream 366exiting the flashline heater 332.

EXAMPLES

The disclosure having been generally described, the following examplesare given as particular embodiments of the disclosure and to demonstratethe practice and advantages thereof. It is understood that theseexamples are given by way of illustration and is not intended to limitthe specification or the claims in any manner.

A computerized commercial process simulator was employed to generatedata in accordance with the embodiments disclosed herein. Each of theexamples below discloses data obtained by simulation of a first pressuredifferential and a second pressure differential according to specifiedoperating conditions. In each of the examples, a CTO valve is associatedwith a first pressure differential, and a flashline heater is associatedwith a second pressure differential, for example, as shown in FIG. 2.Moreover, each example involves a polymerization product transferredthrough the first pressure differential, and portions of the liquidcomponents of the polymerization product vaporize to gas as thepolymerization product transfers through the first and second pressuredifferentials. Each of the examples assumes the drop in pressure of thefirst pressure differential is associated with the CTO valve, and anylines in the first pressure differential are isobaric. Likewise, each ofthe examples assumes the drop in pressure of the second pressuredifferential is associated with the flashline heater, and any lines inthe second pressure differential are isobaric.

Example 1

The operating conditions for Example 1 are disclosed in Table 1 below.As can be seen, the operating conditions include values for the pressuredifferentials, the mass flow rates and composition for thepolymerization product, operating conditions of the CTO valve, the steamtemperature on the flashline heater, and operating conditions of theseparation vessel.

TABLE 1 First Pressure Differential 226.4 psi Second PressureDifferential 247.6 psi Total Pressure 474.0 psi DifferentialPolymerization Product Methane 90.0 lb/hr Ethylene 3149.6 lb/hr Ethane899.9 lb/hr Propane 180.0 lb/hr Isobutane 82070.8 lb/hr Butane 2459.8lb/hr Hexene 1889.8 lb/hr Hexane 180.0 lb/hr Solid Polymer 85,000 lb/hrSolid Polymer 48.4 wt % Continuous Take-Off (CTO) Valve InletTemperature 197.6 ° F. Outlet Temperature 195.9 ° F. Inlet Pressure615.0 psia Outlet Pressure 388.6 psia Vapor Fraction 0.0000 wt SteamTemperature 238 ° F. Separation Vessel Pressure 140 psia Temperature 175° F. Elevation 150 ft

As can be seen in Table 1, the first pressure differential is less thanthe second pressure differential. Particularly, the first pressuredifferential is about 47.8% of the total pressure differential, and thesecond pressure differential is about 52.2% of the total pressuredifferential. The polymerization product entering and exiting the CTOhas 0.0000 wt. % vapor fraction. The particular operating conditions ofthe flashline heater of Example 1 are shown in Table 2.

TABLE 2 Over- Segment Segment Total Outlet Drop in Outlet Vapor Avg allU_(o) Segment Set Length Length Pressure Pressure Temp Fraction VelocityID OD Froude Heated (B/hr- Duty (#) (#) (ft) (ft) (psia) (psi) (° F.)(wt) (ft/sec) (in) (in) No. (y/n) ft²-F.) (1k B/hr) 1 1 10 10 379.7 8.9195.8 0.0000 25.5 3.068 3.500 8.89 n 0.0 0.0 2 1 20 30 364.5 15.2 195.60.0000 25.6 3.068 3.500 8.92 n 0.0 0.0 3 1 20 50 349.3 15.2 195.5 0.000025.6 3.068 3.500 8.92 n 0.0 0.0 4 1 20 70 344.0 5.3 195.3 0.0024 28.23.068 3.500 9.83 n 0.0 0.0 5 1 20 90 337.6 6.4 194.4 0.0174 27.8 3.0683.500 9.69 n 0.0 0.0 6 1 20 110 331.0 6.6 193.4 0.0334 29.4 3.068 3.50010.25 n 0.0 0.0 7 2 20 130 326.0 5.0 193.1 0.0523 31.9 3.068 3.500 11.12y 171.4 114.3 8 2 20 150 321.1 4.9 192.7 0.0713 34.4 3.068 3.500 11.99 y164.4 110.5 9 2 20 170 319.0 2.1 192.8 0.0834 36.1 3.068 3.500 12.58 y158.4 106.8 10 2 20 190 316.7 2.3 192.8 0.0960 37.8 3.068 3.500 13.17 y154.9 104.3 11 2 20 210 314.3 2.4 192.7 0.1089 39.6 3.068 3.500 13.80 y151.4 102.0 12 2 20 230 311.8 2.5 192.6 0.0122 41.5 3.068 3.500 14.46 y148.0 99.8 13 2 20 250 309.0 2.8 192.5 0.1365 43.4 3.068 3.500 15.13 y144.5 97.8 14 2 20 270 303.9 5.1 191.8 0.1574 46.5 3.068 3.500 16.21 y148.6 101.4 15 2 20 290 300.6 3.3 191.6 0.1743 49.0 3.068 3.500 17.08 y161.0 111.0 16 2 20 310 297.0 3.6 191.2 0.1928 51.9 3.068 3.500 18.09 y171.5 119.1 17 2 20 330 293.2 3.8 190.8 0.2130 55.0 3.068 3.500 19.17 y180.2 126.2 18 2 20 350 288.9 4.3 190.3 0.2349 58.5 3.068 3.500 20.39 y187.0 132.4 19 2 20 370 284.3 4.6 189.7 0.2593 62.6 3.068 3.500 21.82 y192.4 133.7 20 2 20 390 279.2 5.1 188.9 0.2853 67.1 3.068 3.500 23.39 y196.5 138.9 21 2 20 410 273.7 5.5 187.9 0.3128 72.1 3.068 3.500 25.13 y199.6 144.0 22 2 20 430 264.8 8.9 186.0 0.3507 80.1 3.068 3.500 27.92 y202.8 154.8 23 2 20 450 257.7 7.1 184.5 0.3848 80.2 3.068 3.500 27.95 y204.6 161.6 24 2 20 470 249.5 8.2 182.6 0.4224 95.7 3.068 3.500 33.35 y206.1 168.3 25 2 20 490 240.2 9.3 180.3 0.4645 106.1 3.068 3.500 36.98 y207.3 176.0 26 2 20 510 229.2 11.0 177.3 0.5128 119.1 3.068 3.500 41.51y 208.1 186.4 27 3 20 530 210.6 18.6 171.2 0.5685 139.9 3.068 3.50048.76 n 0.0 0 28 3 20 550 176.9 33.7 158.7 0.6710 189.6 3.068 3.50066.08 n 0.0 0 29 3 10 560 141.0 35.9 143.0 0.7840 270.2 3.068 3.50094.17 n 0.0 0

As indicated in Table 2, the flashline heater of Example 1 hastwenty-nine segments which have a total length of 560 ft. In Example 1,the flashline heater has a constant inner diameter of 3.068 in. Thefirst six segments (i.e., the first segment set) are not heated, and thelast three segments (i.e., the third segment set) are not heated. Theaverage velocity of polymerization product through the heater rangesfrom about 25.5 ft/sec in the first segment to about 270.2 ft/sec in thetwenty-ninth segment. The Froude number is calculated in each segment ofthe flashline heater, and the Froude number ranges from about 8.89 toabout 94.17. The vapor fraction indicates the vaporization of liquid inthe polymerization product, which creates a liquid-gas-solid mixture inthe flashline heater of the second pressure differential. As can be seenin Table 2, the vapor fraction is 0.7840 after the last segment of theflashline heater. The residence time of the polymerization product inthe flashline heater is about 11.98 seconds.

Example 2

The operating conditions for Example 2 are disclosed in Table 3 below.The same parameters as in Table 1 are shown, with values specific forExample 2.

TABLE 3 First Pressure Differential 233.8 psi Second PressureDifferential 245.5 psi Total Pressure 479.3 psi DifferentialPolymerization Product Methane 63.5 lb/hr Ethylene 2223.3 lb/hr Ethane635.2 lb/hr Propane 127.0 lb/hr Isobutane 57932.3 lb/hr Butane 1524.5lb/hr Hexene 1334.0 lb/hr Hexane 127.0 lb/hr Solid Polymer 60,000 lb/hrSolid Polymer 48.4 wt % Continuous Take-Off (CTO) Valve InletTemperature 197.6 ° F. Outlet Temperature 195.8 ° F. Inlet Pressure615.0 psia Outlet Pressure 381.2 psia Vapor Fraction 0.0000 wt SteamTemperature 238 ° F. Separation Vessel Pressure 140 psia Temperature 175° F. Elevation 150 ft

As can be seen in Table 3, the first pressure differential is less thanthe second pressure differential. Particularly, the first pressuredifferential is about 48.8% of the total pressure differential, and thesecond pressure differential is about 51.2% of the total pressuredifferential. The polymerization product entering and exiting the CTOhas 0.0000 wt. % vapor fraction. The particular operating conditions ofthe flashline heater of Example 2 are shown in Table 4.

TABLE 4 Over- Segment Segment Total Outlet Drop in Outlet Vapor Avg allU_(o) Segment Set Length Length Pressure Pressure Temp Fraction VelocityID OD Froude Heated (B/hr- Duty (#) (#) (ft) (ft) (psia) (psi) (° F.)(wt) (ft/sec) (in) (in) No. (y/n) ft²-F.) (1k B/hr) 1 1 10 10 357.5 23.7195.5 0.0000 39.8 2.067 2.375 16.90 n 0.0 0.0 2 1 20 30 347.3 10.2 195.40.0000 53.6 2.067 2.375 22.76 n 0.0 0.0 3 1 20 50 339.1 8.2 194.5 0.013142.2 2.067 2.375 17.92 n 0.0 0.0 4 1 20 70 328.6 10.5 192.9 0.0381 46.82.067 2.375 19.87 n 0.0 0.0 5 1 20 90 318.5 10.1 191.2 0.0663 52 2.0672.375 22.08 n 0.0 0.0 6 1 20 110 301.9 16.6 188.3 0.1042 61.5 2.0672.375 26.11 n 0.0 0.0 7 2 20 130 295.3 6.6 187.5 0.1297 47.3 2.469 2.87518.38 y 153.9 92.7 8 2 20 150 288.1 7.2 186.6 0.1579 52.5 2.469 2.87520.40 y 159.2 97.5 9 2 20 170 282.9 5.2 186.0 0.1830 56.7 2.469 2.87522.03 y 178.2 110.8 10 2 20 190 276.8 6.1 185.2 0.2119 62.4 2.469 2.87524.24 y 191.4 120.6 11 2 20 210 269.9 6.9 184.2 0.2445 68.9 2.469 2.87526.77 y 200.3 128.5 12 2 20 230 261.9 8.0 182.8 0.2821 76.7 2.469 2.87529.80 y 206.4 132.2 13 2 20 250 252.6 9.3 180.9 0.3244 86.3 2.469 2.87533.53 y 210.6 142.6 14 2 20 270 238.1 14.5 177.4 0.3836 101.6 2.4692.875 39.47 y 214.1 152.2 15 3 20 290 233.7 4.4 176.7 0.4155 70.6 3.0683.500 24.61 y 181.9 166.5 16 3 20 310 228.9 4.8 175.7 0.4495 76.2 3.0683.500 26.56 y 182.8 169.8 17 3 20 330 223.5 5.4 174.5 0.4859 82.9 3.0683.500 28.89 y 183.5 173.7 18 3 20 350 217.0 6.5 172.8 0.5263 90.4 3.0683.500 31.51 y 184.1 178.2 19 3 20 370 206.5 10.5 169.7 0.5799 102.03.068 3.500 35.55 y 184.6 186.4 20 3 20 390 191.1 15.4 164.6 0.6500121.0 3.068 3.500 42.17 y 184.7 198.8 21 3 20 410 172.7 18.4 159.90.7309 147.2 3.068 3.500 51.30 y 184.0 214.8 22 4 20 430 167.6 5.1 156.20.7728 92.3 4.026 4.500 28.08 y 140.7 226.8 23 4 20 450 162.9 4.7 154.70.8131 99.2 4.026 4.500 30.18 y 140.2 230.4 24 4 20 470 158.1 4.8 153.30.8533 106.5 4.026 4.500 32.40 y 139.7 233.8 25 4 20 490 153.4 4.7 151.80.8928 114.7 4.026 4.500 34.90 y 139.2 235.9 26 4 20 510 148.6 4.8 150.40.9318 123.0 4.026 4.500 37.42 y 138.7 240.1 27 5 20 530 144.1 4.5 148.40.9440 128.0 4.026 4.500 38.94 n 0.0 0 28 5 20 550 139.7 4.4 146.40.9563 133.7 4.026 4.500 40.68 n 0.0 0 29 5 10 560 135.7 4.0 144.70.9678 139.1 4.026 4.500 42.32 n 0.0 0

As indicated in Table 4, the flashline heater of Example 2 hastwenty-nine segments which have a total length of 560 ft. In Example 2,the flashline heater has an inner diameter which increases along thelength of the flashline heater. Particularly, the segments of the firstsegment set have an inner diameter of 2.067 in. The segments of thesecond segment set have an inner diameter of 2.469 in. The segments ofthe third segment set have an inner diameter of 3.068 in. The segmentsof the fourth segment set have an inner diameter of 4.026 in. Thesegments of the fifth segment set also have an inner diameter of 4.026in and differ from the fourth segment set in that the segments of thefifth segment set are not heated. The first six segments (i.e., thefirst segment set) are also not heated. The average velocity ofpolymerization stream through the heater ranges from about 39.8 ft/secin the first segment to about 147.2 ft/sec in the twenty-first segment.The Froude number is calculated in each segment of the flashline heater,and the Froude number ranges from about 16.9 to about 51.3. As can beseen in Table 4, the vapor fraction is 0.9678 after the last segment ofthe flashline heater. The residence time of the polymerization productin the flashline heater is about 7.52 seconds.

Example 3

The operating conditions for Example 3 are disclosed in Table 5 below.The same parameters as in Tables 1 and 3 are shown, with values specificfor Example 3.

TABLE 5 First Pressure Differential 202.7 psi Second PressureDifferential 271.3 psi Total Pressure 474.0 psi DifferentialPolymerization Product Methane 36.2 lb/hr Ethylene 1266.2 lb/hr Ethane361.8 lb/hr Propane 72.4 lb/hr Isobutane 32994.4 lb/hr Butane 868.3lb/hr Hexene 759.7 lb/hr Hexane 72.4 lb/hr Solid Polymer 34,172 lb/hrSolid Polymer 48.4 wt % Continuous Take-Off (CTO) Valve InletTemperature 197.6 ° F. Outlet Temperature 196.0 ° F. Inlet Pressure615.0 psia Outlet Pressure 412.3 psia Vapor Fraction 0.0000 wt SteamTemperature 238 ° F. Separation Vessel Pressure 140 psia Temperature 175° F. Elevation 150 ft

As can be seen in Table 5, the first pressure differential is less thanthe second pressure differential. Particularly, the first pressuredifferential is about 42.7% of the total pressure differential, and thesecond pressure differential is about 57.3% of the total pressuredifferential. The polymerization product entering and exiting the CTOhas 0.0000 wt. % vapor fraction. The particular operating conditions ofthe flashline heater of Example 3 are shown in Table 6.

TABLE 6 Over- Segment Segment Total Outlet Drop in Outlet Vapor Avg allU_(o) Segment Set Length Length Pressure Pressure Temp Fraction VelocityID OD Froude Heated (B/hr- Duty (#) (#) (ft) (ft) (psia) (psi) (° F.)(wt) (ft/sec) (in) (in) No. (y/n) ft²-F.) (1k B/hr) 1 1 10 10 376.7 35.6195.7 0.0000 42.9 1.500 1.900 21.38 n 0.0 0.0 2 1 20 30 361.9 14.8 195.50.0000 60.1 1.500 1.900 29.96 n 0.0 0.0 3 1 20 50 344.4 17.5 195.20.0000 69.6 1.500 1.900 34.69 n 0.0 0.0 4 1 20 70 333.0 11.4 193.50.0258 48.3 1.500 1.900 24.07 n 0.0 0.0 5 1 20 90 318.1 14.9 191.00.0617 56.1 1.500 1.900 27.96 n 0.0 0.0 6 1 20 110 293.2 24.9 186.50.1239 72.1 1.500 1.900 35.94 n 0.0 0.0 7 2 20 130 285.7 7.5 185.70.1562 48.5 1.939 2.375 21.26 y 152.5 74.8 8 2 20 150 277.2 8.5 184.60.1939 55.0 1.939 2.375 24.11 y 173.4 86.7 9 2 20 170 270.0 7.2 183.70.2312 61.6 1.939 2.375 27.01 y 188.6 96.1 10 2 20 190 261.4 8.6 182.40.2750 69.8 1.939 2.375 30.60 y 196.9 99.8 11 2 20 210 251.2 10.2 180.50.3252 80.2 1.939 2.375 35.16 y 202.1 108.4 12 2 20 230 238.7 12.5 177.60.3842 93.7 1.939 2.375 41.08 y 205.5 115 13 2 20 250 222.7 16.0 173.50.4566 112.7 1.939 2.375 49.41 y 207.8 124 14 2 20 270 191.4 31.3 163.40.5801 156.7 1.939 2.375 68.70 y 209.8 140.3 15 3 20 290 186.5 4.9 162.20.6288 68.7 3.068 3.500 23.94 y 144.7 164.1 16 3 20 310 180.9 5.6 160.70.6806 75.6 3.068 3.500 26.35 y 144.6 167.8 17 3 20 330 175.1 5.8 159.00.7331 82.8 3.068 3.500 28.86 y 144.2 171 18 3 20 350 169.2 5.9 157.20.7862 90.9 3.068 3.500 31.68 y 143.8 174.3 19 3 20 370 163.2 6.0 155.40.8391 100.1 3.068 3.500 34.89 y 143.2 177.8 20 3 20 390 157.3 5.9 153.70.8917 109.6 3.068 3.500 38.20 y 142.6 180.6 21 3 20 410 151.3 6.0 152.10.9426 119.8 3.068 3.500 41.75 y 141.9 183.3 22 4 20 430 149.7 1.6 152.40.9788 72.7 4.026 4.500 22.12 y 103.6 177.4 23 4 20 450 148.3 1.4 154.51.0000 75.4 4.026 4.500 22.94 y 103.5 171.1 24 4 20 470 147.1 1.2 159.11.0000 77.3 4.026 4.500 23.52 y 103.7 164.2 25 4 20 490 145.8 1.3 163.41.0000 79.2 4.026 4.500 24.10 y 104.3 155.9 26 4 20 510 144.6 1.2 167.51.0000 81.0 4.026 4.500 24.64 y 104.9 147.9 27 5 20 530 143.3 1.3 167.41.0000 81.8 4.026 4.500 24.89 n 0.0 0 28 5 20 550 142.1 1.2 167.3 1.000082.6 4.026 4.500 25.13 n 0.0 0 29 5 10 560 141.0 1.1 167.2 1.0000 83.44.026 4.500 25.37 n 0.0 0

As indicated in Table 6, the flashline heater of Example 3 hastwenty-nine segments which have a total length of 560 ft. In Example 3,the flashline heater has an inner diameter which increases along thelength of the flashline heater. Particularly, the segments of the firstsegment set have an inner diameter of 1.500 in. The segments of thesecond segment set have an inner diameter of 1.939 in. The segments ofthe third segment set have an inner diameter of 3.068 in. The segmentsof the fourth segment set have an inner diameter of 4.026 in. Thesegments of the fifth segment set also have an inner diameter of 4.026in and differ from the fourth segment set in that the segments of thefifth segment set are not heated. The first six segments (i.e., thefirst segment set) are also not heated. The average velocity ofpolymerization product through the heater ranges from about 42.9 ft/secin the first segment to about 156.7 ft/sec in the fourteenth segment.The Froude number is calculated in each segment of the flashline heater,and the Froude number ranges from about 21.26 to about 68.7. As can beseen in Table 6, the vapor fraction is 1.0000 after the last segment ofthe flashline heater. The residence time of the polymerization productin the flashline heater is about 7.53 seconds.

Example 4

The operating conditions for Example 4 are disclosed in Table 7 below.The same parameters as in Tables 1, 3, and 5 are shown, with valuesspecific for Example 4.

TABLE 7 First Pressure Differential 221.7 psi Second PressureDifferential 251.8 psi Total Pressure 473.5 psi DifferentialPolymerization Product Methane 36.2 lb/hr Ethylene 1266.2 lb/hr Ethane361.8 lb/hr Propane 72.4 lb/hr Isobutane 32994.4 lb/hr Butane 868.3lb/hr Hexene 759.7 lb/hr Hexane 72.4 lb/hr Solid Polymer 34,172 lb/hrSolid Polymer 48.4 wt % Continuous Take-Off (CTO) Valve InletTemperature 197.6 ° F. Outlet Temperature 195.9 ° F. Inlet Pressure615.0 psia Outlet Pressure 393.3 psia Vapor Fraction 0.0000 wt SteamTemperature 222 ° F. Separation Vessel Pressure 140 psia Temperature 175° F. Elevation 150 ft

As can be seen in Table 7, the first pressure differential is less thanthe second pressure differential. Particularly, the first pressuredifferential is about 46.8% of the total pressure differential, and thesecond pressure differential is about 53.2% of the total pressuredifferential. The polymerization product entering and exiting the CTOhas 0.0000 wt. % vapor fraction. The particular operating conditions ofthe flashline heater of Example 4 are shown in Table 8.

TABLE 8 Over- Segment Segment Total Outlet Drop in Outlet Vapor Avg allU_(o) Segment Set Length Length Pressure Pressure Temp Fraction VelocityID OD Froude Heated (B/hr- Duty (#) (#) (ft) (ft) (psia) (psi) (° F.)(wt) (ft/sec) (in) (in) No. (y/n) ft²-F.) (1k B/hr) 1 1 30 30 359.3 34.0195.6 0.0000 25.7 1.939 2.375 11.27 n 0.0 0.0 2 1 30 60 349.8 9.5 195.50.0000 31.1 1.939 2.375 13.63 n 0.0 0.0 3 1 30 90 340.3 9.5 194.7 0.070826.9 1.939 2.375 11.79 n 0.0 0.0 4 1 30 120 331.1 9.2 193.4 0.0326 29.71.939 2.375 13.02 n 0.0 0.0 5 1 30 150 322.5 8.6 192.0 0.0537 32.3 1.9392.375 14.16 n 0.0 0.0 6 1 30 180 315.9 6.6 190.9 0.0698 34.6 1.939 2.37515.17 n 0.0 0.0 7 2 40 220 310.7 5.2 190.9 0.0987 34.1 2.067 2.375 14.48y 160.1 98.8 8 2 40 260 304.5 6.2 19.7 0.1304 38.1 2.067 2.375 16.18 y151.0 93.5 9 2 40 300 297.2 7.3 190.1 0.1672 43.0 2.067 2.375 18.26 y155.7 97.7 10 2 40 340 288.2 9.0 189.2 0.2128 49.4 2.067 2.375 20.98 y179.0 115.2 11 2 40 380 277.2 11.0 187.6 0.2698 58.0 2.067 2.375 24.63 y197.7 126.7 12 2 40 420 263.1 14.1 185.1 0.3395 69.7 2.067 2.375 29.60 y207.9 148.1 13 2 40 460 244.4 18.7 180.9 0.4286 87.0 2.067 2.375 36.94 y213.6 168.6 14 2 40 500 213.5 30.9 182.2 0.5625 120.9 2.067 2.375 51.34y 217.2 201.1 15 3 30 530 207.1 6.4 170.7 0.6169 61.0 3.068 3.500 21.26y 146.1 165.9 16 3 30 560 199.1 8.0 168.5 0.6774 68.5 3.068 3.500 23.87y 146.1 173.5 17 3 30 590 190.8 8.3 166.1 0.7397 76.6 3.068 3.500 26.70y 145.8 181.3 18 3 30 620 182.4 8.4 163.6 0.8032 86.2 3.068 3.500 30.04y 145.2 188.8 19 3 30 650 173.8 8.6 161.1 0.8671 96.7 3.068 3.500 33.70y 144.5 195.8 20 3 30 680 165.3 8.5 158.6 0.9298 108.2 3.068 3.500 37.71y 143.6 202.7 21 3 30 710 157.0 8.3 156.4 0.9901 120.8 3.068 3.500 42.10y 142.7 209.1 22 4 30 740 154.9 2.1 160.5 1.0000 72.9 4.026 4.500 22.18y 104.1 192.3 23 4 30 770 153.1 1.8 165.4 1.0000 75.0 4.026 4.500 22.82y 104.6 178.8 24 4 30 800 151.2 1.9 169.9 1.0000 77.2 4.026 4.500 23.49y 105.3 164.9 25 4 30 830 149.4 1.8 174.1 1.0000 79.3 4.026 4.500 24.13y 106.0 152 26 4 30 860 147.5 1.9 177.8 1.0000 81.4 4.026 4.500 24.77 y106.6 140.1 27 5 30 890 145.7 1.8 177.7 1.0000 82.6 4.026 4.500 25.13 n0.0 0 28 5 30 920 143.8 1.9 177.5 1.0000 83.8 4.026 4.500 25.50 n 0.0 029 5 30 950 141.5 2.3 177.3 1.0000 85.4 4.026 4.500 25.98 n 0.0 0

As indicated in Table 8, the flashline heater of Example 4 hastwenty-nine segments which have a total length of 950 ft. In Example 4,the flashline heater has an inner diameter which increases along thelength of the flashline heater. Particularly, the segments of the firstsegment set have an inner diameter of 1.939 in. The segments of thesecond segment set have an inner diameter of 2.067 in. The segments ofthe third segment set have an inner diameter of 3.068 in. The segmentsof the fourth segment set have an inner diameter of 4.026 in. Thesegments of the fifth segment set also have an inner diameter of 4.026in and differ from the fourth segment set in that the segments of thefifth segment set are not heated. The first six segments (i.e., thefirst segment set) are also not heated. The average velocity ofpolymerization product through the heater ranges from about 25.7 ft/secto about 120.9 ft/sec. The Froude number is calculated in each segmentof the flashline heater, and the Froude number ranges from about 11.27to about 51.34. As can be seen in Table 8, the vapor fraction is 1.0000after the last segment of the flashline heater. The residence time ofthe polymerization product in the flashline heater of Example 4 is about17.59 seconds.

Example 5

The operating conditions for Example 5 are disclosed in Table 9 below.The same parameters as in Tables 1, 3, 5, and 7 are shown, with valuesspecific for Example 5.

TABLE 9 First Pressure Differential 267.2 psi Second PressureDifferential 206.1 psi Total Pressure 473.3 psi Differential SlurryComposition Methane 68.0 lb/hr Ethylene 2674.5 lb/hr Ethane 784.3 lb/hrPropane 166.5 lb/hr Isobutane 78012.5 lb/hr Butane 2068.0 lb/hr Hexene1860.4 lb/hr Hexane 177.4 lb/hr Solid Polymer 85,000 lb/hr Solid Polymer48.4 wt % Continuous Take-Off (CTO) Valve Inlet Temperature 197.6 ° F.Outlet Temperature 195.4 ° F. Inlet Pressure 615.0 psia Outlet Pressure347.8 psia Vapor Fraction 0.0531 wt Steam Temperature 238 ° F.Separation Vessel Pressure 140 psia Temperature 175 ° F. Elevation 150ft

As can be seen in Table 9, the first pressure differential is greaterthan the second pressure differential. Particularly, the first pressuredifferential is about 56.5% of the total pressure differential, and thesecond pressure differential is about 43.5% of the total pressuredifferential. The polymerization product exiting the CTO is a mixturehaving about 5.31% vapor phase by weight of the mixture. The particularoperating conditions of the flashline heater of Example 5 are shown inTable 10.

TABLE 10 Over- Segment Segment Total Outlet Drop in Outlet Vapor Avg allU_(o) Segment Set Length Length Pressure Pressure Temp Fraction VelocityID OD Froude Heated (B/hr- Duty (#) (#) (ft) (ft) (psia) (psi) (° F.)(wt) (ft/sec) (in) (in) No. (y/n) ft²-F.) (1k B/hr) 1 1 10 10 343.5 4.3195.2 0.0028 27.0 3.068 3.500 9.41 n 0.0 0.0 2 1 20 30 337.3 6.2 194.30.0176 27.8 3.068 3.500 9.69 n 0.0 0.0 3 1 20 50 332.3 5.0 193.5 0.029529.0 3.068 3.500 10.11 n 0.0 0.0 4 1 20 70 327.5 4.8 192.8 0.0411 30.53.068 3.500 10.63 n 0.0 0.0 5 1 20 90 322.8 4.7 192.0 0.0527 32.1 3.0683.500 11.19 n 0.0 0.0 6 1 20 110 316.2 6.6 190.9 0.0689 34.3 3.068 3.50011.95 n 0.0 0.0 7 2 20 130 311.2 5.0 190.5 0.0883 37.0 3.068 3.500 12.90y 157.6 111.2 8 2 20 150 306.2 5.0 190.0 0.1082 39.9 3.068 3.500 13.91 y151.5 107.9 9 2 20 170 303.6 2.6 189.9 0.1219 41.9 3.068 3.500 14.60 y146.1 104.7 10 2 20 190 300.7 2.9 189.7 0.1362 44.0 3.068 3.500 15.34 y142.6 102.5 11 2 20 210 297.7 3.0 189.5 0.1516 46.3 3.068 3.500 16.14 y147.3 106.3 12 2 20 230 294.4 3.3 189.3 0.1685 48.9 3.068 3.500 17.04 y159.9 116.0 13 2 20 250 290.9 3.5 188.9 0.1872 51.8 3.068 3.500 18.05 y170.9 124.7 14 2 20 270 284.8 6.1 188.0 0.2138 56.2 3.068 3.500 19.59 y181.0 133.8 15 2 20 290 280.4 4.4 187.5 0.2367 60.1 3.068 3.500 20.95 y188.8 141.7 16 2 20 310 275.6 4.8 186.8 0.2614 64.4 3.068 3.500 22.45 y193.7 147.2 17 2 20 330 270.3 5.3 186.0 0.2887 69.3 3.068 3.500 24.15 y197.5 148.4 18 2 20 350 264.4 5.9 184.9 0.3178 75.3 3.068 3.500 26.24 y200.6 154.0 19 2 20 370 257.8 6.6 183.6 0.3499 81.8 3.068 3.500 28.51 y202.9 163.4 20 2 20 390 250.4 7.4 181.9 0.3852 89.6 3.068 3.500 31.23 y204.7 169.6 21 2 20 410 241.9 8.5 179.9 0.4244 98.8 3.068 3.500 34.43 y206.1 176.6 22 2 20 430 229.1 12.8 176.4 0.4779 113.1 3.068 3.500 39.42y 207.6 187.7 23 2 20 450 216.2 12.9 172.6 0.5335 129.8 3.068 3.50045.24 y 208.2 199.7 24 2 20 470 188.4 27.8 163.1 0.6361 170.2 3.0683.500 59.32 y 209.1 222.5 25 3 20 490 179.2 9.2 160.0 0.6847 110.7 4.0264.500 33.68 y 165.2 251.8 26 3 20 510 169.8 9.4 156.6 0.7350 123.9 4.0264.500 37.70 y 164.6 261.7 27 4 20 530 160.3 9.5 152.5 0.7641 135.6 4.0264.500 41.26 n 0.0 0.0 28 4 20 550 150.6 9.7 148.2 0.7944 149.1 4.0264.500 45.36 n 0.0 0.0 29 4 10 560 141.7 8.9 144.1 0.8221 163.1 4.0264.500 49.62 n 0.0 0.0

As indicated in Table 10, the flashline heater of Example 5 hastwenty-nine segments which have a total length of 560 ft. In Example 5,the flashline heater has an inner diameter which increases along thelength of the flashline heater. Particularly, the segments of the firstsegment set have an inner diameter of 3.068 in. The segments of thesecond segment set have an inner diameter of 3.068 in. The segments ofthe third segment set have an inner diameter of 4.026 in. The segmentsof the fourth segment set have an inner diameter of 4.026 in. The firstsix segments (i.e., the first segment set) and the fourth segment setare not heated. The second segment set and the third segment set areheated. The average velocity of polymerization product through theheater ranges from about 27.0 ft/sec to about 163.1 ft/sec. The Froudenumber is calculated in each segment of the flashline heater, and theFroude number ranges from about 9.41 to about 59.32. The residence timeof the polymerization product in the flashline heater of Example 5 isabout 10.19 seconds.

Example 6

The operating conditions for Example 6 are disclosed in Table 11 below.The same parameters as in Tables 1, 3, 5, 7, and 9 are shown, withvalues specific for Example 6.

TABLE 11 First Pressure Differential 274.6 psi Second PressureDifferential 196.7 psi Total Pressure 471.3 psi Differential SlurryComposition Methane 51.3 lb/hr Ethylene 1968.2 lb/hr Ethane 573.8 lb/hrPropane 120.1 lb/hr Isobutane 55879.3 lb/hr Butane 1478.4 lb/hr Hexene1319.7 lb/hr Hexane 125.8 lb/hr Solid Polymer 60,000 lb/hr Solid Polymer48.4 wt % Continuous Take-Off (CTO) Valve Inlet Temperature 197.6 ° F.Outlet Temperature 194.8 ° F. Inlet Pressure 615.0 psia Outlet Pressure340.4 psia Vapor Fraction 0.0383 wt Steam Temperature 238 ° F.Separation Vessel Pressure 140 psia Temperature 175 ° F. Elevation 150ft

As can be seen in Table 11, the first pressure differential is greaterthan the second pressure differential. Particularly, the first pressuredifferential is about 58.3% of the total pressure differential, and thesecond pressure differential is about 41.7% of the total pressuredifferential. The polymerization product exiting the CTO is a mixturehaving about 3.83% vapor phase by weight of the mixture. The particularoperating conditions of the flashline heater of Example 6 are shown inTable 12.

TABLE 12 Over- Segment Segment Total Outlet Drop in Outlet Vapor Avg allU_(o) Segment Set Length Length Pressure Pressure Temp Fraction VelocityID OD Froude Heated (B/hr- Duty (#) (#) (ft) (ft) (psia) (psi) (° F.)(wt) (ft/sec) (in) (in) No. (y/n) ft²-F.) (1k B/hr) 1 1 10 10 334.4 6.0193.9 0.0247 31.1 2.469 2.875 12.08 n 0.0 0.0 2 1 20 30 328.8 5.6 193.00.0383 32.8 2.469 2.875 12.74 n 0.0 0.0 3 1 20 50 323.2 5.6 192.1 0.051934.8 2.469 2.875 13.52 n 0.0 0.0 4 1 20 70 317.5 5.7 191.1 0.0658 36.92.469 2.875 14.34 n 0.0 0.0 5 1 20 90 311.8 5.7 190.1 0.0802 39.1 2.4692.875 15.19 n 0.0 0.0 6 1 20 110 303.3 8.5 188.6 0.1016 42.6 2.469 2.87516.55 n 0.0 0.0 7 2 20 130 296.7 6.6 187.9 0.1270 46.8 2.469 2.875 18.18y 154.9 92.6 8 2 20 150 289.7 7.0 186.9 0.1546 51.5 2.469 2.875 20.01 y158.2 96.2 9 2 20 170 284.5 5.2 186.4 0.1792 55.9 2.469 2.875 21.72 y175.8 108.5 10 2 20 190 278.6 5.9 185.7 0.2074 61.5 2.469 2.875 23.89 y189.6 118.6 11 2 20 210 271.8 6.8 184.7 0.2394 67.7 2.469 2.875 26.30 y199.1 126.6 12 2 20 230 264.0 7.8 183.3 0.2763 75.3 2.469 2.875 29.25 y205.6 130.3 13 2 20 250 255.0 9.0 181.6 0.3175 84.4 2.469 2.875 32.79 y210.0 140.7 14 2 20 270 240.9 14.1 178.2 0.3752 99.0 2.469 2.875 38.46 y213.7 150.1 15 3 20 290 236.7 4.2 177.5 0.4063 68.8 3.068 3.500 23.98 y181.6 164.0 16 3 20 310 232.0 4.7 176.6 0.4394 74.0 3.068 3.500 25.79 y182.6 167.1 17 3 20 330 226.8 5.2 175.5 0.4748 80.3 3.068 3.500 27.99 y183.4 170.8 18 3 20 350 221.0 5.8 174.1 0.5128 87.2 3.068 3.500 30.39 y184.0 174.9 19 3 20 370 211.9 9.1 171.5 0.5616 97.1 3.068 3.500 33.84 y184.5 182.0 20 3 20 390 198.2 13.7 167.2 0.6258 113.2 3.068 3.500 39.45y 184.9 192.6 21 3 20 410 180.3 17.9 160.8 0.7043 136.6 3.068 3.50047.61 y 184.5 207.5 22 4 20 430 175.2 5.1 159.3 0.7451 85.6 4.026 4.50026.04 y 141.3 219.2 23 4 20 450 170.6 4.6 157.9 0.7846 91.8 4.026 4.50027.93 y 140.9 222.7 24 4 20 470 166.0 4.6 156.5 0.8242 98.5 4.026 4.50029.97 y 140.5 226.0 25 4 20 490 161.3 4.7 155.0 0.8636 105.5 4.026 4.50032.10 y 140.0 229.3 26 4 20 510 156.6 4.7 153.6 0.9026 113.4 4.026 4.50034.50 y 139.5 231.4 27 5 20 530 152.2 4.4 151.7 0.9153 118.0 4.026 4.50035.90 n 0.0 0.0 28 5 20 550 147.7 4.5 149.8 0.9278 123.0 4.026 4.50037.42 n 0.0 0.0 29 5 10 560 143.7 4.0 148.0 0.9386 127.8 4.026 4.50038.88 n 0.0 0.0

As indicated in Table 12, the flashline heater of Example 6 hastwenty-nine segments which have a total length of 560 ft. In Example 6,the flashline heater has an inner diameter which increases along thelength of the flashline heater. Particularly, the segments of the firstsegment set have an inner diameter of 2.469 in and are not heated. Thesegments of the second segment set have an inner diameter of 2.469 inand are heated. The segments of the third segment set have an innerdiameter of 3.068 in and are heated. The segments of the fourth segmentset have an inner diameter of 4.026 in and are heated. The segments ofthe fifth segment set have an inner diameter of 4.026 in are not heated.The average velocity of polymerization product through the heater rangesfrom about 31.1 ft/sec to about 136.6 ft/sec. The Froude number iscalculated in each segment of the flashline heater, and the Froudenumber ranges from about 12.08 to about 39.45. The residence time of thepolymerization product in the flashline heater of Example 6 is about8.53 seconds.

Example 7

The operating conditions for Example 7 are disclosed in Table 13 below.The same parameters as in Tables 1, 3, 5, 7, 9, and 11 are shown, withvalues specific for Example 7.

TABLE 13 First Pressure Differential 267.2 psi Second PressureDifferential 203.3 psi Total Pressure 470.5 psi Differential SlurryComposition Methane 27.4 lb/hr Ethylene 1075.2 lb/hr Ethane 315.3 lb/hrPropane 66.9 lb/hr Isobutane 31362.9 lb/hr Butane 831.4 lb/hr Hexene747.9 lb/hr Hexane 71.3 lb/hr Solid Polymer 34,172 lb/hr Solid Polymer48.4 wt % Continuous Take-Off (CTO) Valve Inlet Temperature 197.6 ° F.Outlet Temperature 195.4 ° F. Inlet Pressure 615.0 psia Outlet Pressure347.8 psia Vapor Fraction 0.0531 wt Steam Temperature 238 ° F.Separation Vessel Pressure 140 psia Temperature 175 ° F. Elevation 150ft

As can be seen in Table 13, the first pressure differential is greaterthan the second pressure differential. Particularly, the first pressuredifferential is about 56.8% of the total pressure differential, and thesecond pressure differential is about 43.2% of the total pressuredifferential. The polymerization product exiting the CTO is a mixturehaving 5.31% vapor phase by weight of the mixture. The particularoperating conditions of the flashline heater of Example 7 are shown inTable 14.

TABLE 14 Over- Segment Segment Total Outlet Drop in Outlet Vapor Avg allU_(o) Segment Set Length Length Pressure Pressure Temp Fraction VelocityID OD Froude Heated (B/hr- Duty (#) (#) (ft) (ft) (psia) (psi) (° F.)(wt) (ft/sec) (in) (in) No. (y/n) ft²-F.) (1k B/hr) 1 1 10 10 337.8 10.0194.3 0.0162 46.3 1.500 1.900 23.08 n 0.0 0.0 2 1 20 30 322.7 15.1 191.90.0523 53.9 1.500 1.900 26.87 n 0.0 0.0 3 1 20 50 306.8 15.9 189.20.0916 63.1 1.500 1.900 31.45 n 0.0 0.0 4 1 20 70 287.3 19.5 185.40.1415 77.2 1.500 1.900 38.48 n 0.0 0.0 5 2 20 90 279.6 7.7 183.8 0.161649.7 1.939 2.375 21.79 n 0.0 0.0 6 2 20 110 268.8 10.8 181.5 0.1906 55.61.939 2.375 24.38 n 0.0 0.0 7 3 20 130 259.1 9.7 180.0 0.2355 64.1 1.9392.375 28.10 y 190.2 103.2 8 3 20 150 247.7 11.4 177.9 0.2883 75.1 1.9392.375 32.92 y 199.0 108.9 9 3 20 170 236.3 11.4 175.6 0.3438 87.6 1.9392.375 38.40 y 203.6 118.4 10 3 20 190 221.9 14.4 172.0 0.4108 104.81.939 2.375 45.94 y 206.5 126.0 11 3 20 210 202.6 19.3 166.3 0.4967131.6 1.939 2.375 57.69 y 208.3 137.5 12 4 20 230 199.8 2.8 166.1 0.536856.6 3.068 3.500 19.73 y 144.5 156.4 13 4 20 250 196.1 3.7 165.4 0.580761.4 3.068 3.500 21.40 y 144.9 157.8 14 4 20 270 190.7 5.4 164.1 0.630167.3 3.068 3.500 23.46 y 145.0 160.2 15 4 20 290 185.1 5.6 162.6 0.681073.9 3.068 3.500 25.76 y 144.9 164.0 16 4 20 310 179.4 5.7 161.0 0.732680.8 3.068 3.500 28.16 y 144.6 167.1 17 4 20 330 173.6 5.8 159.3 0.784788.5 3.068 3.500 30.84 y 144.1 170.3 18 4 20 350 167.7 5.9 157.5 0.836997.2 3.068 3.500 33.88 y 143.6 173.5 19 4 20 370 161.8 5.9 155.8 0.8886106.2 3.068 3.500 37.01 y 143.0 176.5 20 4 20 390 155.9 5.9 154.3 0.9387115.8 3.068 3.500 40.36 y 142.3 179.1 21 5 20 410 154.5 1.4 154.6 0.974170.1 4.026 4.500 21.33 y 104.1 173.5 22 5 20 430 152.9 1.6 156.1 1.000072.9 4.026 4.500 22.18 y 103.9 167.8 23 5 20 450 151.7 1.2 160.6 1.000074.7 4.026 4.500 22.73 y 104.0 161.5 24 5 20 470 150.5 1.2 164.8 1.000076.5 4.026 4.500 23.27 y 104.6 153.3 25 5 20 490 149.3 1.2 168.8 1.000078.2 4.026 4.500 23.79 y 105.2 145.4 26 5 20 510 148.0 1.3 172.5 1.000079.8 4.026 4.500 24.28 y 105.8 138.0 27 6 20 530 146.8 1.2 172.4 1.000080.6 4.026 4.500 24.52 n 0.0 0.0 28 6 20 550 145.6 1.2 172.3 1.0000 81.44.026 4.500 24.77 n 0.0 0.0 29 6 10 560 144.5 1.1 172.2 1.0000 82.14.026 4.500 24.98 n 0.0 0.0

As indicated in Table 14, the flashline heater of Example 7 hastwenty-nine segments which have a total length of 560 ft. In Example 7,the flashline heater has an inner diameter which increases along thelength of the flashline heater. Particularly, the segments of the firstsegment set have an inner diameter of 1.500 in and are not heated. Thesegments of the second segment set have an inner diameter of 1.939 inand are not heated. The segments of the third segment set have an innerdiameter of 1.939 in and are heated. The segments of the fourth segmentset have an inner diameter of 3.068 in and are heated. The segments ofthe fifth segment set have an inner diameter of 4.026 in and are heated.The segments of the sixth segment set have an inner diameter of 4.026 inand are not heated. The average velocity of polymerization productthrough the heater ranges from about 46.3 ft/sec to about 131.6 ft/sec.The Froude number is calculated in each segment of the flashline heater,and the Froude number ranges from about 21.33 to about 57.69. Theresidence time of the polymerization product in the flashline heater ofExample 7 is about 7.57 seconds.

Example 8

The operating conditions for Example 8 are disclosed in Table 15 below.The same parameters as in Tables 1, 3, 5, 7, 9, 11, and 13 are shown,with values specific for Example 8.

TABLE 15 First Pressure Differential 263.5 psi Second PressureDifferential 213.3 psi Total Pressure 476.8 psi Differential SlurryComposition Methane 26.3 lb/hr Ethylene 996.8 lb/hr Ethane 289.9 lb/hrPropane 60.3 lb/hr Isobutane 28016.9 lb/hr Butane 740.9 lb/hr Hexene660.2 lb/hr Hexane 62.9 lb/hr Solid Polymer 30,000 lb/hr Solid Polymer48.4 wt % Continuous Take-Off (CTO) Valve Inlet Temperature 197.6 ° F.Outlet Temperature 195.5 ° F. Inlet Pressure 615.0 psia Outlet Pressure351.5 psia Vapor Fraction 0.0353 wt Steam Temperature 222 ° F.Separation Vessel Pressure 140 psia Temperature 175 ° F. Elevation 150ft

As can be seen in Table 15, the first pressure differential is greaterthan the second pressure differential. Particularly, the first pressuredifferential is about 55.3% of the total pressure differential, and thesecond pressure differential is about 44.7% of the total pressuredifferential. The polymerization product exiting the CTO is a mixturehaving 3.53% vapor phase by weight of the mixture. The particularoperating conditions of the flashline heater of Example 8 are shown inTable 16.

TABLE 16 Over- Segment Segment Total Outlet Drop in Outlet Vapor Avg allU_(o) Segment Set Length Length Pressure Pressure Temp Fraction VelocityID OD Froude Heated (B/hr- Duty (#) (#) (ft) (ft) (psia) (psi) (° F.)(wt) (ft/sec) (in) (in) No. (y/n) ft²-F.) (1k B/hr) 1 1 30 30 341.7 9.8195.0 0.0072 24.8 1.939 2.375 10.87 n 0.0 0.0 2 1 30 60 333.4 8.3 193.70.0270 25.3 1.939 2.375 11.09 n 0.0 0.0 3 1 30 90 325.7 7.7 192.5 0.045627.4 1.939 2.375 12.01 n 0.0 0.0 4 1 30 120 318.0 7.7 191.2 0.0646 29.71.939 2.375 13.02 n 0.0 0.0 5 1 30 150 310.1 7.9 189.8 0.0844 32.3 1.9392.375 14.16 n 0.0 0.0 6 1 30 180 304.1 6.0 188.7 0.0993 34.3 1.939 2.37515.04 n 0.0 0.0 7 2 40 220 299.3 4.8 188.9 0.1291 33.5 2.067 2.375 14.22y 140.2 92.6 8 2 40 260 293.7 5.6 188.7 0.1628 37.2 2.067 2.375 15.80 y144.2 95.3 9 2 40 300 286.9 6.8 188.3 0.2045 42.6 2.067 2.375 18.09 y167.7 111.7 10 2 40 340 278.6 8.3 187.6 0.2547 49.1 2.067 2.375 20.85 y185.6 125.8 11 2 40 380 268.5 10.1 186.2 0.3139 57.3 2.067 2.375 24.33 y195.9 132.3 12 2 40 420 255.7 12.8 183.9 0.3855 68.3 2.067 2.375 29.00 y201.9 149.6 13 2 40 460 239.1 16.6 180.1 0.4743 83.9 2.067 2.375 35.62 y205.6 166.8 14 2 40 500 194.3 44.8 166.1 0.6575 132.0 2.067 2.375 56.05y 209.1 207.7 15 3 30 530 187.9 6.4 164.5 0.7184 66.7 3.068 3.500 23.25y 136.7 175.8 16 3 30 560 181.4 6.5 162.7 0.7802 74.0 3.068 3.500 25.79y 36.3 180.7 17 3 30 590 174.8 6.6 161.0 0.8423 82.0 3.068 3.500 28.58 y35.7 185.5 18 3 30 620 168.2 6.6 159.3 0.9035 90.7 3.068 3.500 31.61 y35.1 189.9 19 3 30 650 161.8 6.4 157.8 0.9630 99.9 3.068 3.500 34.82 y34.4 192.5 20 3 30 680 155.8 6.0 158.9 1.0000 108.7 3.068 3.500 37.88 y33.7 188.5 21 3 30 710 150.2 5.6 164.2 1.0000 115.4 3.068 3.500 40.22 y33.5 178.1 22 4 30 740 148.7 1.5 169.1 1.0000 69.0 4.026 3.500 20.99 y97.7 156.0 23 4 30 770 147.3 1.4 173.6 1.0000 70.7 4.026 4.500 21.51 y98.4 143.1 24 4 30 800 145.8 1.5 177.6 1.0000 72.4 4.026 4.500 22.03 y99.1 131.2 25 4 30 830 144.4 1.4 181.3 1.0000 74.0 4.026 4.500 22.51 y99.7 120.1 26 4 30 860 142.9 1.5 184.7 1.0000 75.6 4.026 4.500 23.00 y100.2 110.0 27 5 30 890 141.5 1.4 184.6 1.0000 76.5 4.026 4.500 23.27 n0.0 0 28 5 30 920 140.0 1.5 184.5 1.0000 77.4 4.026 4.500 23.55 n 0.0 029 5 30 950 138.2 1.8 184.4 1.0000 78.6 4.026 4.500 23.91 n 0.0 0

As indicated in Table 16, the flashline heater of Example 8 hastwenty-nine segments which have a total length of 950 ft. In Example 8,the flashline heater has an inner diameter which increases along thelength of the flashline heater. Particularly, the segments of the firstsegment set have an inner diameter of 1.939 in and are not heated. Thesegments of the second segment set have an inner diameter of 2.067 inand are heated. The segments of the third segment set have an innerdiameter of 3.068 in and are heated. The segments of the fourth segmentset have an inner diameter of 4.026 in and are heated. The segments ofthe fifth segment set have an inner diameter of 4.026 in are not heated.The average velocity of polymerization product through the heater rangesfrom about 24.8 ft/sec to about 132.0 ft/sec. The Froude number iscalculated in each segment of the flashline heater, and the Froudenumber ranges from about 10.87 to about 56.05. The residence time of thepolymerization product in the flashline heater of Example 8 is about18.02 seconds.

Additional Description

Processes and systems for the production for pressure management of apolymerization product flowing from a loop polymerization reactor to aseparation vessel in a slurry polymerization system have been described.The following are a first set of nonlimiting, specific embodiments inaccordance with the present disclosure:

A first embodiment, which is a process for pressure management of apolymerization product in slurry polymerization, comprising withdrawingthe polymerization product from a loop polymerization reactor, andconveying the withdrawn polymerization product to a separation vesselvia a first pressure differential and a second pressure differential,wherein the withdrawn polymerization product flows through the firstpressure differential before flowing through the second pressuredifferential, wherein the first pressure differential is less than thesecond pressure differential.

A second embodiment is the process of the first embodiment, wherein thefirst pressure differential has a drop in pressure between about 5% toabout 50% of a total pressure differential between the looppolymerization reactor and the separation vessel, wherein the secondpressure differential has a drop in pressure between about 50% to about95% of the total pressure differential between the loop polymerizationreactor and the separation vessel.

A third embodiment is the process of the second embodiment, wherein thedrop in pressure of the first pressure differential is greater than 40%and less than 50% of the total pressure differential, wherein the dropin pressure of the second pressure differential is greater than 50% andless than 60% of the total pressure differential.

A fourth embodiment is the process of the second through thirdembodiments, wherein the drop in pressure of the first pressuredifferential is from a pressure of the loop polymerization reactor to apressure less than the pressure of the loop polymerization reactor.

A fifth embodiment is the process of the first through fourthembodiments, wherein the first pressure differential is associated witha first line comprising a continuous take-off valve, wherein the secondpressure differential is associated with a second line comprising aflashline heater.

A sixth embodiment is the process of the fifth embodiment, wherein thecontinuous take-off valve has a diameter of about 1 inch to about 8inches, wherein the flashline heater has an inner diameter of about 2inches to about 10 inches.

A seventh embodiment is the process of the fifth through sixthembodiments, wherein the flashline heater comprises a plurality ofsegments, wherein at least one of the plurality of segments has an innerdiameter greater than a preceding segment of the plurality of segments.

An eighth embodiment is the process of the first through seventhembodiments, where the process further comprises conveying a mixturethrough the second pressure differential so that the mixture has aFroude number in a range from about 5 to about 100, wherein the mixturecomprises a solid polymer and a vapor phase of at least a portion of adiluent.

A ninth embodiment is a process for pressure management of apolymerization product in slurry polymerization, comprising withdrawinga polymerization product slurry from a loop polymerization reactor,conveying the polymerization product slurry through a first linecomprising a continuous take-off valve to yield a mixture, and conveyingthe mixture through a second line comprising a flashline heater so thatthe mixture has a Froude number in a range from about 5 to about 100.

A tenth embodiment is the process of the ninth embodiment, wherein adrop in pressure of the first line is less than a drop in pressure ofthe second line.

An eleventh embodiment is the process of the fifth through seventh andninth through tenth embodiments, wherein the Froude number of themixture conveyed through the flashline heater is in a range of about 15to about 30.

A twelfth embodiment is the process of the ninth through eleventhembodiments, wherein the flashline heater comprises a plurality ofsegments.

A thirteenth embodiment is the process of the ninth through twelfthembodiments, wherein the conveying the mixture through the second linecomprising the flashline heater comprises conveying the mixture throughat least one segment of the plurality of segments of the flashlineheater so that the mixture has a Froude number in a range from about 5to about 100 in the at least one segment.

A fourteenth embodiment is the process of the seventh and twelfththrough thirteenth embodiments, wherein each of the plurality ofsegments has an inner diameter of about 2 inches to about 10 inches.

A fifteenth embodiment is the process of the twelfth through fourteenthembodiments, wherein at least one of the plurality of segments has aninner diameter greater than an inner diameter of a preceding segment ofthe plurality of segments.

A sixteenth embodiment is the process of the fifth through seventh andninth through fifteenth embodiments, wherein the flashline heater has alength and an inner diameter such that the mixture has a residence timein the flashline heater of greater than about 7 seconds.

A seventeenth embodiment is the process of the ninth through sixteenthembodiments, wherein the continuous take-off valve has a diameter ofabout 1 inch to about 8 inches.

An eighteenth embodiment is the process of the ninth through seventeenthembodiments, wherein the polymerization product slurry comprises a solidpolymer and a liquid phase of a diluent, wherein the mixture comprisesthe solid polymer and a vapor phase of at least a portion of thediluent.

A nineteenth embodiment, which is a process for pressure management of apolymerization product slurry withdrawn from a loop polymerizationreactor in slurry polymerization, comprising, conveying thepolymerization product slurry through a continuous take-off valve,converting the polymerization product slurry to a mixture, and conveyingthe mixture through a flashline heater, wherein the mixture in theflashline heater has a Froude number in a range of 5 to 100.

A twentieth embodiment is the process of the fifth through seventh andnineteenth embodiments, wherein the mixture conveyed through theflashline heater has a Froude number in a range of 15 to 30.

A twenty-first embodiment is the process of the nineteenth and twentiethembodiments, wherein a drop in pressure of a first line comprising thecontinuous take-off valve is less than a drop in pressure of a secondline comprising the flashline heater.

A twenty-second embodiment is the process of the nineteenth throughtwenty-first embodiments, wherein the polymerization product slurrycomprises a solid polymer and a liquid phase of a diluent, wherein themixture comprises the solid polymer and a vapor phase of at least aportion of the diluent.

A twenty-third embodiment is the process of the eighteenth andtwenty-second embodiments, wherein the solid polymer comprisespolyethylene, wherein the diluent comprises isobutane.

A twenty-fourth embodiment is the process of the nineteenth throughtwenty-third embodiments, wherein the flashline heater comprises aplurality of segments, wherein each of the plurality of segments has aninner diameter of about 2 inches to about 10 inches.

A twenty-fifth embodiment is the process of the twenty-fourthembodiment, wherein at least one of the plurality of segments has aninner diameter greater than an inner diameter of a preceding segment ofthe plurality of segments.

A twenty-sixth embodiment is the process of the nineteenth throughtwenty-fifth embodiments, wherein the flashline heater has a length andan inner diameter such that the mixture has a residence time in theflashline heater of greater than about 7 seconds.

A twenty-seventh embodiment is the process of the nineteenth throughtwenty-sixth embodiments, wherein the continuous take-off valve has adiameter of about 1 inch to about 8 inches.

A twenty-eighth embodiment, which is a process for pressure managementof a polymerization product flowing from a loop polymerization reactorto a separation vessel in slurry polymerization, comprising conveyingthe polymerization product through a first line having a first pressuredifferential, wherein the first line comprises a continuous take-offvalve, conveying the polymerization product through a second line havinga second pressure differential, wherein the second line comprises aflashline heater, wherein the second line is downstream of the firstline, wherein the first pressure differential is less than the secondpressure differential.

A twenty-ninth embodiment is the process of the fifth throughtwenty-eighth embodiments, wherein at least a portion of the second linehas an inner diameter greater than an inner diameter of the first line.

A thirtieth embodiment is the process of the fifth through seventh andninth through twenty-ninth embodiments, wherein the flashline heatercomprises a plurality of segments, wherein at least one segment of theplurality of segments has an inner diameter greater than a diameter ofthe continuous take-off valve.

A thirty-first embodiment is the process of the twenty-eighth throughtwenty-ninth embodiments, wherein the flashline heater comprises aplurality of segments, wherein at least one segment of the plurality ofsegments has an inner diameter greater than an inner diameter of apreceding segment of the plurality of segments.

A thirty-second embodiment is the process of the twenty-eighth throughthirty-first embodiments, wherein the continuous take-off valve has adiameter of about 1 inch to about 8 inches, wherein each of the segmentshas an inner diameter of about 2 inches to about 10 inches.

A thirty-third embodiment is the process of the twenty-eighth throughthirty-second embodiments, wherein the first pressure differential has adrop in pressure between about 5% to about 50% of a total pressuredifferential between the loop polymerization reactor and the separationvessel, wherein the second pressure differential has a drop in pressurebetween about 50% to about 95% of the total pressure differentialbetween the loop polymerization reactor and the separation vessel.

A thirty-fourth embodiment is the process of the thirty-thirdembodiment, wherein the drop in pressure of the first pressuredifferential is greater than 40% and less than 50% of the total pressuredifferential, wherein the drop in pressure of the second pressuredifferential is greater than 50% and less than 60% of the total pressuredifferential.

A thirty-fifth embodiment, which is a process for pressure management ofa polymerization product flowing from a loop polymerization reactor to aseparation vessel in slurry polymerization, comprising conveying thepolymerization product through a continuous take-off valve, andconveying the polymerization product through a flashline heater, whereinthe polymerization product has a residence time in the flashline heaterof greater than about 7 seconds, wherein a drop in pressure of a firstline comprising the continuous take-off valve is less than a drop inpressure of a second line comprising the flashline heater.

A thirty-sixth embodiment is the process of the fifth through seventhand ninth through thirty-fifth embodiments, wherein a velocity of thepolymerization product in the flashline heater is below a sonic velocityof the polymerization product.

A thirty-seventh embodiment is the process of the thirty-fifth throughthirty-sixth embodiments, wherein the flashline heater comprises aplurality of segments.

A thirty-eighth embodiment is the process of the thirty-seventhembodiment, wherein each of the plurality of segments has an innerdiameter of about 2 inches to about 10 inches.

A thirty-ninth embodiment is the process of the thirty-seventh throughthirty-eighth embodiments, wherein at least one of the plurality ofsegments has an inner diameter greater than a preceding segment of theplurality of segments.

A fortieth embodiment is the process of the seventh through thirty-ninthembodiments, wherein the conveying the polymerization product throughthe flashline heater comprises conveying the polymerization productthrough the plurality of segments of the flashline heater at a velocitybelow a sonic velocity of the polymerization product.

A forty-first embodiment is the process of the thirty-fifth throughfortieth embodiments, wherein the continuous take-off valve has adiameter of about 1 inch to about 8 inches.

A forty-second embodiment, which is a system for pressure management ofa polymerization product in a loop polymerization process, which mayoptionally incorporate the processes embodied by the first throughforty-first embodiments, the system comprising a polymerization reactorto form the polymerization product, a first line comprising a continuoustake-off valve, wherein the first line receives a polymerization productslurry from the loop slurry polymerization reactor, wherein a firstpressure differential is associated with the first line, a second linecomprising a flashline heater, wherein the second line receives amixture from the first line, wherein a second pressure differential isassociated with the second line, and a separation vessel to receive asolid polymer from the second line, wherein the solid polymer isrecovered from the separation vessel, wherein the first pressuredifferential is less than the second pressure differential.

A forty-third embodiment is the system of the forty-second embodiment,wherein the polymerization product slurry comprises the solid polymerand a liquid phase of a diluent, wherein the mixture comprises solidpolymer and a vapor phase of at least a portion of the diluent.

A forty-fourth embodiment is the system of the forty-second throughforty-third embodiments, wherein the first pressure differential has adrop in pressure between about 5% to about 50% of a total pressuredifferential between the loop polymerization reactor and the separationvessel, wherein the second pressure differential has a drop in pressurebetween about 50% to about 95% of the total pressure differentialbetween the loop polymerization reactor and the separation vessel.

A forty-fifth embodiment is the system of the forty-fourth embodiment,wherein the drop in pressure of the first pressure differential isgreater than 40% and less than 50% of the total pressure differential,wherein the drop in pressure of the second pressure differential isgreater than 50% and less than 60% of the total pressure differential.

A forty-sixth embodiment is the system of the forty-second throughforty-fifth embodiments, wherein the flashline heater comprises aplurality of segments, wherein at least one segment of the plurality ofsegments has an inner diameter greater than an inner diameter of apreceding segment of the plurality of segments.

A forty-seventh embodiment is the system of the forty-sixth embodiment,wherein each of the segments has an inner diameter of about 2 inches toabout 10 inches.

A forty-eighth embodiment is the system of the forty-second throughforty-seventh embodiments, wherein the continuous take-off valve has adiameter of about 1 inch to about 8 inches.

A forty-ninth embodiment is the system of the forty-second throughforty-eighth embodiments, wherein the mixture conveyed through theflashline heater has a Froude number in a range from about 5 to about100.

A fiftieth embodiment is the system of the forty-second throughforty-ninth embodiments, wherein the mixture in the flashline heater hasa velocity less than a sonic velocity of the mixture.

A fifty-first embodiment, which is the process of the nineteenthembodiment, wherein at least a portion of the product slurry isconverted to the mixture is a line between the continuous take-off valveand the flashline heater.

A fifty-second embodiment, which is the process of nineteenthembodiment, wherein none of the product slurry is converted to themixture prior to entering the flashline heater.

A fifty-third embodiment, which is the process of fifty-firstembodiment, wherein at least a portion of the product slurry isconverted to the mixture in the flashline heater.

A fifty-fourth embodiment, which is the process of fifty-secondembodiment, wherein at least a portion of the product slurry isconverted to the mixture in the flashline heater.

A fifty-fifth embodiment, which is the process of the twenty-firstembodiment, wherein none of the product slurry is converted to themixture in the first line.

A fifty-sixth embodiment, which is the process of the twenty-firstembodiment, wherein at least a portion of the product slurry isconverted to the mixture in the second line.

A fifty-seventh embodiment, which is a process for pressure managementof a polymerization product in slurry polymerization, compriseswithdrawing a polymerization product slurry from a loop polymerizationreactor; conveying the polymerization product slurry through a firstline comprising a continuous take-off valve to yield a mixturecomprising a vapor phase, wherein the mixture exits the continuoustake-off valve; and conveying the mixture through a second linecomprising a flashline heater so that the mixture has a Froude number ina range from about 5 to about 100.

A fifty-eighth embodiment, which is the process of the fifty-seventhembodiment, wherein a drop in pressure of the first line is greater thanor less than a drop in pressure of the second line.

A fifty-ninth embodiment, which is the process of the fifty-sevenththrough fifty-eighth embodiments, wherein the Froude number of themixture conveyed through the flashline heater is in a range of about 10to about 60.

A sixtieth embodiment, which is the process of the fifty-seventh throughfifty-ninth embodiments, wherein the flashline heater comprises aplurality of segments.

A sixty-first embodiment, which is the process of the sixtiethembodiment, wherein the conveying the mixture through the second linecomprising the flashline heater comprises conveying the mixture throughat least one segment of the plurality of segments of the flashlineheater so that the mixture has a Froude number in a range from about 5to about 100 in the at least one segment.

A sixty-second embodiment, which is the process of the sixtieth throughsixty-first embodiments, wherein each of the plurality of segments hasan inner diameter of about 2 inches to about 10 inches.

A sixty-third embodiment, which is the process of the sixtieth throughsixty-second embodiments, wherein at least one of the plurality ofsegments has an inner diameter greater than an inner diameter of apreceding segment of the plurality of segments.

A sixty-fourth embodiment, which is the process of the fifty-sevenththrough sixty-third embodiments, wherein the flashline heater has alength and one or more inner diameters such that the flashline heaterprovides the polymerization product a residence time of greater thanabout 7.5 seconds.

A sixty-fifth embodiment, which is the process of the fifty-sevenththrough sixty-fourth embodiments, wherein the vapor phase of the mixturemay comprise greater than 0% by weight of the mixture in the first line.

A sixty-sixth embodiment, which is the process of the fifty-sevenththrough sixty-fifth embodiments, wherein the polymerization productslurry comprises a solid polymer and a liquid phase of a diluent,wherein the mixture further comprises the solid polymer, wherein thevapor phase of the mixture comprises at least a portion of the diluent.

A sixty-seventh embodiment, which is a process for pressure managementof a polymerization product slurry withdrawn from a loop polymerizationreactor in slurry polymerization, comprising: conveying thepolymerization product slurry through a continuous take-off valve;converting the polymerization product slurry to a mixture comprising avapor phase, wherein the mixture exits the continuous take-off valve;and conveying the mixture through a flashline heater, wherein themixture conveyed through the flashline heater has a Froude number in arange of about 5 to about 100.

A sixty-eighth embodiment, which is the process of the sixty-seventhembodiment, wherein the mixture conveyed through the flashline heaterhas a Froude number in a range of about 10 to about 60.

A sixty-ninth embodiment, which is the process of the sixty-sevenththrough sixty-eight embodiments, wherein a drop in pressure of a firstline comprising the continuous take-off valve is greater than or lessthan a drop in pressure of a second line comprising the flashlineheater.

A seventieth embodiment, which is the process of the sixty-sevenththrough the sixty-ninth embodiments, wherein the polymerization productslurry comprises a solid polymer and a liquid phase of a diluent,wherein the mixture further comprises the solid polymer, and wherein thevapor phase of the mixture comprises at least a portion of the diluent.

A seventy-first embodiment, which is the process of the seventiethembodiment, wherein the solid polymer comprises polyethylene, whereinthe diluent comprises isobutane.

A seventy-second embodiment, which is the process of the sixty-sevenththrough seventy-first embodiments, wherein the flashline heatercomprises a plurality of segments, wherein each of the plurality ofsegments has an inner diameter of about 1 inches to about 10 inches.

A seventy-third embodiment, which is the process of the seventy-secondembodiment, wherein at least one of the plurality of segments has aninner diameter greater than an inner diameter of a preceding segment ofthe plurality of segments.

A seventy-fourth embodiment, which is the process of the sixty-sevenththrough seventy-third embodiments, wherein the flashline heater has alength and one or more inner diameters such that the flashline heaterprovides a residence time of greater than about 7.5 seconds.

A seventy-fifth embodiment, which is the process of the sixty-sevenththrough the seventy-fourth embodiments, wherein the continuous take-offvalve has a diameter of about 1 inch to about 8 inches.

A seventy-sixth embodiment, which is the process of the sixty-sevenththrough seventy-fifth embodiments, wherein the vapor phase of themixture may comprise greater than 0% by weight of the mixture whichexits the continuous-take off valve.

Processes and systems for the production for pressure management of apolymerization product flowing from a loop polymerization reactor to aseparation vessel in a slurry polymerization system have been described.

While preferred embodiments of the invention have been shown anddescribed, modifications thereof can be made by one skilled in the artwithout departing from the spirit and teachings of the invention. Theembodiments described herein are exemplary only, and are not intended tobe limiting. Many variations and modifications of the inventiondisclosed herein are possible and are within the scope of the invention.Where numerical ranges or limitations are expressly stated, such expressranges or limitations should be understood to include iterative rangesor limitations of like magnitude falling within the expressly statedranges or limitations (e.g., from about 1 to about 10 includes, 2, 3, 4,etc.; greater than 0.10 includes 0.11, 0.12, 0.13, etc.). Use of theterm “optionally” with respect to any element of a claim is intended tomean that the subject element is required, or alternatively, is notrequired. Both alternatives are intended to be within the scope of theclaim. Use of broader terms such as comprises, includes, having, etc.should be understood to provide support for narrower terms such asconsisting of, consisting essentially of, comprised substantially of,etc.

Accordingly, the scope of protection is not limited by the descriptionset out above but is only limited by the claims which follow, that scopeincluding all equivalents of the subject matter of the claims. Each andevery claim is incorporated into the specification as an embodiment ofthe present invention. Thus, the claims are a further description andare an addition to the preferred embodiments of the present invention.The discussion of a reference in the disclosure is not an admission thatit is prior art to the present invention, especially any reference thatmay have a publication date after the priority date of this application.The disclosures of all patents, patent applications, and publicationscited herein are hereby incorporated by reference, to the extent thatthey provide exemplary, procedural or other details supplementary tothose set forth herein.

What is claimed is:
 1. A process for pressure management of apolymerization product in slurry polymerization, the process comprising:withdrawing a polymerization product slurry from a loop polymerizationreactor; conveying the polymerization product slurry through a firstline comprising a continuous take-off valve to yield a mixturecomprising a vapor phase, wherein the mixture exits the continuoustake-off valve; and conveying the mixture through a second linecomprising a flashline heater so that the mixture has a Froude number ina range from about 5 to about
 100. 2. The process of claim 1, wherein adrop in pressure of the first line is less than a drop in pressure ofthe second line.
 3. The process of claim 1, wherein a drop in pressureof the first line is greater than a drop in pressure of the second line.4. The process of claim 1, wherein the Froude number of the mixtureconveyed through the flashline heater is in a range of about 10 to about60.
 5. The process of claim 1, wherein the flashline heater comprises aplurality of segments.
 6. The process of claim 5, wherein the conveyingthe mixture through the second line comprising the flashline heatercomprises: conveying the mixture through at least one segment of theplurality of segments of the flashline heater so that the mixture has aFroude number in a range from about 5 to about 100 in the at least onesegment.
 7. The process of claim 5, wherein at least one of theplurality of segments has an inner diameter greater than an innerdiameter of a preceding segment of the plurality of segments.
 8. Theprocess of claim 1, wherein the flashline heater has a length and one ormore inner diameters such that the flashline heater provides thepolymerization product a residence time of greater than about 7.5seconds.
 9. The process of claim 1, wherein the vapor phase of themixture may comprise greater than 0% by weight of the mixture in thefirst line.
 10. The process of claim 1, wherein the polymerizationproduct slurry comprises a solid polymer and a liquid phase of adiluent, wherein the mixture further comprises the solid polymer,wherein the vapor phase of the mixture comprises at least a portion ofthe diluent.
 11. A process for pressure management of a polymerizationproduct slurry withdrawn from a loop polymerization reactor in slurrypolymerization, the process comprising: conveying the polymerizationproduct slurry through a continuous take-off valve; converting thepolymerization product slurry to a mixture comprising a vapor phase,wherein the mixture exits the continuous take-off valve; and conveyingthe mixture through a flashline heater, wherein the mixture conveyedthrough the flashline heater has a Froude number in a range of 5 to 100.12. The process of claim 11, wherein the mixture conveyed through theflashline heater has a Froude number in a range of 10 to
 60. 13. Theprocess of claim 11, wherein a drop in pressure of a first linecomprising the continuous take-off valve is less than a drop in pressureof a second line comprising the flashline heater.
 14. The process ofclaim 11, wherein a drop in pressure of a first line comprising thecontinuous take-off valve is greater than a drop in pressure of a secondline comprising the flashline heater.
 15. The process of claim 11,wherein the polymerization product slurry comprises a solid polymer anda liquid phase of a diluent, wherein the mixture further comprises thesolid polymer, and wherein the vapor phase of the mixture comprises atleast a portion of the diluent.
 16. The process of claim 15, wherein thesolid polymer comprises polyethylene, wherein the diluent comprisesisobutane.
 17. The process of claim 11, wherein the flashline heatercomprises a plurality of segments, wherein at least one of the pluralityof segments has an inner diameter greater than an inner diameter of apreceding segment of the plurality of segments.
 18. The process of claim11, wherein the flashline heater has a length and one or more innerdiameters such that the flashline heater provides a residence time ofgreater than about 7.5 seconds.
 19. The process of claim 11, wherein thecontinuous take-off valve has a diameter of about 1 inch to about 8inches.
 20. The process of claim 11, wherein the vapor phase of themixture may comprise greater than 0% by weight of the mixture whichexits the continuous-take off valve.